Semiempirical formula for the estimation of organic radical ion mobility in liquid n-alkanes

Borovkov VI

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Semiempirical formula for the estimation of organic radical ion mobility in liquid n-alkanes

【24h】

Semiempirical formula for the estimation of organic radical ion mobility in liquid n-alkanes

机译：估计液态正构烷烃中有机自由基离子迁移率的半经验公式

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The mobilities of radical ions of a series of organic compounds in n-alkanes with viscosities within the range of 0.2-4 cP were determined by applying the method of time-resolved electric field effect. The obtained data were used to express the correlation between the mobilities and solvent viscosity in the form of the modified Stokes-Einstein relation. The relation was parametrized in such a way that the specific molecular properties of both solvent and solute appear in the expression only as the ratio of the volumes of their molecules. A significant difference between aromatic and aliphatic compounds was found with respect to the dependence of radical ion mobility on this volume ratio, and two different parametrizations were suggested for mobility estimation in these cases.

机译：采用时间分辨电场效应的方法，确定了一系列有机化合物在正构烷烃中的自由基迁移率，粘度在0.2-4 cP范围内。使用获得的数据以改进的斯托克斯-爱因斯坦关系的形式表示迁移率和溶剂粘度之间的相关性。该关系被参数化，使得溶剂和溶质两者的特定分子性质仅以其分子体积的比例出现在表达中。在自由基离子迁移率对该体积比的依赖性方面，发现芳香族化合物和脂肪族化合物之间存在显着差异，在这些情况下，为迁移率估计提出了两种不同的参数。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2006年第50期|共4页
作者
Borovkov VI;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
TRANSLATIONAL DIFFUSION; PARAMAGNETIC RELAXATION; DELAYED FLUORESCENCE; NONPOLAR LIQUIDS; CATIONS; RECOMBINATION; COEFFICIENTS; MOLECULES; ANIONS; HEXANE;

机译：翻译扩散;顺磁弛豫;延迟荧光;非极性液体;阳离子;重组;系数;分子;阴离子;正己烷;

相似文献

外文文献
中文文献
专利

1. Semiempirical formula for the estimation of organic radical ion mobility in liquid n-alkanes [J] . Borovkov VI The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第50期

机译：估计液态正构烷烃中有机自由基离子迁移率的半经验公式
2. Molecular Mobility Effect on Magnetic Interactions in All-Organic Paramagnetic Liquid Crystal with Nitroxide Radical as a Hydrogen-Bonding Acceptor [J] . Nakagami Sho, Akita Takuya, Kiyohara Daichi, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2018,第29期

机译：分子迁移率对全有机顺磁液晶中的磁相互作用，其具有氢粘结受体的硝基氧化物
3. Effective Rate Constants and Uptake Coefficients for the Reactions of Organic Molecular Markers (n-Alkanes, Hopanes, and Steranes) in Motor Oil and Diesel Primary Organic Aerosols with Hydroxyl Radicals [J] . ANDREW T. LAMBE, MARISSA A. MIRACOLO, CHRISTOPHER J. HENNIGAN, Environmental Science & Technology . 2009,第23期

机译：机油和柴油一次有机气溶胶与羟基自由基反应中有机分子标记（正构烷烃，Hop烷和甾烷）的有效速率常数和吸收系数
4. Effect of Room-Temperature Ionic Liquids as Replacements for Volatile Organic Solvents in Free-Radical Polymerization [C] . Michael G. Benton, Christopher S. Brazel American Chemical Society (ACS) National Meeting Symposium "Green (or Greener) Industrial Applications of Ionic Liquids", Apr 1-5, 2001, San Diego, California . 2001

机译：室温离子液体对自由基聚合中挥发性有机溶剂的替代作用
5. I. Theoretical investigations of spin-spin interactions: Semiempirical estimations of exchange parameters for diradical metalloporphyrin cations and zero-field splitting parameters for conjugated diradicals. II. Synthesis and characterization of radical-substituted metalloporphyrins: Precursors for potential molecular magnetic building blocks. [D] . Sandberg, Kay Aycock. 1998

机译：一，自旋-自旋相互作用的理论研究：双自由基金属卟啉阳离子交换参数和共轭双自由基零场分裂参数的半经验估计。二。自由基取代的金属卟啉的合成与表征：潜在分子磁性构件的前体。
6. Anaerobic Initial Reaction of n-Alkanes in a Denitrifying Bacterium: Evidence for (1-Methylpentyl)succinate as Initial Product and for Involvement of an Organic Radical in n-Hexane Metabolism [O] . Ralf Rabus, Heinz Wilkes, Astrid Behrends, 2001

机译：正构烷烃在反硝化细菌中的厌氧初始反应：（1-甲基戊基）琥珀酸酯为初始产物和有机自由基参与正己烷代谢的证据
7. Products and Mechanism of Secondary Organic Aerosol Formation from Reactions of n-Alkanes with OH Radicals in the Presence of NOx [O] . -1

机译：NOx存在下正烷烃反应的二次有机气溶胶形成的产品及机理
8. Non-linear effects in the radiolysis-optically detected ESR of radical-ion pairs in liquid and glassy solutions. Reactions and motion of organic radicals as studied by ESR and OD ESR spectroscopy [R] . Antzutkin, O. 1992

机译：辐射分解中的非线性效应 - 光学检测液体和玻璃状溶液中自由基离子对的EsR。通过EsR和OD EsR光谱研究有机基团的反应和运动

Semiempirical formula for the estimation of organic radical ion mobility in liquid n-alkanes

摘要

著录项

相似文献

相关主题

期刊订阅