Infrared Spectrum of the CH3-PtH Complex in Solid Argon Prepared in the Oxidative C-H Insertion of Methane by Laser-Ablated Pt Atoms

Han-Gook Cho; Lester Andrews

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Infrared Spectrum of the CH3-PtH Complex in Solid Argon Prepared in the Oxidative C-H Insertion of Methane by Laser-Ablated Pt Atoms

【24h】

Infrared Spectrum of the CH3-PtH Complex in Solid Argon Prepared in the Oxidative C-H Insertion of Methane by Laser-Ablated Pt Atoms

机译：激光烧蚀Pt原子氧化甲烷甲烷插入甲烷时制得的固态氩中CH3-PtH配合物的红外光谱

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Reactions of laser-ablated Pt atoms with CH4 during condensation in excess argon form CH3-PtH through oxidative C-H insertion show and that the late transition-metal atom Pt is an effective methane activation reagent,in agreement with gas phase investigations.Six observed infrared absorptions correlate with the six strongest calculated harmonic frequencies.The computed C-Pt bond length is slightly shorter than those of Pt complexes with large ligands.In addition,the strongest absorption of the CH2=PtH2 methylidene is detected.

机译：激光烧蚀的Pt原子与过量的氩气通过CH3氧化插入CH3-PtH缩合时与CH4的反应表明，后期的过渡金属原子Pt是一种有效的甲烷活化剂，与气相研究一致。六个观察到的红外吸收与六个最强的计算谐波频率相关。计算的C-Pt键长略短于具有大配体的Pt配合物。此外，检测到CH2 = PtH2亚甲基的最强吸收。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2008年第48期|共3页
作者
Han-Gook Cho; Lester Andrews;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Infrared Spectrum of the CH3-PtH Complex in Solid Argon Prepared in the Oxidative C-H Insertion of Methane by Laser-Ablated Pt Atoms [J] . Han-Gook Cho, Lester Andrews The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第48期

机译：激光烧蚀Pt原子氧化甲烷甲烷插入甲烷时制得的固态氩中CH3-PtH配合物的红外光谱
2. Infrared Spectra of Platinum Insertion and Methylidene Complexes Prepared in Oxidative C-H(X) Reactions of Laser-Ablated Pt Atoms with Methane, Ethane, and Halomethanes [J] . Cho HG, Andrews L Organometallics . 2009,第5期

机译：激光烧蚀的Pt原子与甲烷，乙烷和卤代甲烷的氧化C-H（X）反应中制备的铂插入和亚甲基配合物的红外光谱
3. Infrared Spectroscopic Studies of Mono-,Di-,and Trihydrido C-H Insertion Complexes Formed in Reaction of Ethylene with Laser-Ablated Hafnium Atoms and Isolated in a Solid Argon Matrix [J] . Han-Gook Cho, lester Andrews The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2004,第47期

机译：乙烯与激光烧蚀Ha原子反应并在固态氩气基质中分离的单，二和三氢C-H插入配合物的红外光谱研究
4. Infrared Spectrums Research of Nanocrystalline Antimony-Doped Tin oxide Prepared via Chemical Coprecipitation Method [C] . Haiyan Guo, Xi Shao, Zhen Yang ISTM/2007;International symposium on test and measurement . 2007

机译：化学共沉淀法制备纳米晶掺锑氧化锡的红外光谱研究
5. THE VISUAL AND NEAR-INFRARED SPECTRUM OF METHANE AND ITS APPLICATION TO URANUS, NEPTUNE, TRITON AND PLUTO [D] . BENNER, DRAYTON CHRIS. -1

机译：甲烷的可见和近红外光谱及其在天王星，海王星，AND和冥王星中的应用
6. Infrared Absorption Spectrum of Methane From 2470 to 3200 cm−1 [O] . Earle K. Plyler, Eugene D. Tidwell, Lamdin R. Blaine 1960

机译：2470至3200 cm-1的甲烷的红外吸收光谱
7. Infrared spectra of small insertion and methylidene complexes in reactions of laser-ablated palladium atoms with halomethanes [O] . Cho, Han-Gook, Andrews, Lester, Vlaisavljevich, Bess, 2009

机译：激光烧蚀钯原子与卤代甲烷反应中小插入和亚甲基配合物的红外光谱
8. Four Techniques to Measure Complex Refractive Indices of Liquids and Solids at Carbon Dioxide Laser Wavelengths in the Infrared Spectral Region. [R] . Wieliczka, D. M., Querry, M. R. 1990

机译：红外光谱区二氧化碳激光波长测量液体和固体复合折射率的四种技术。

Infrared Spectrum of the CH3-PtH Complex in Solid Argon Prepared in the Oxidative C-H Insertion of Methane by Laser-Ablated Pt Atoms

摘要

著录项

相似文献

相关主题

期刊订阅