Phase Diagram of the B-BN System at 5 GPa

Vladimir L. Solozhenko; Oleksandr O. Kurakevych; Vladimir Z. Turkevich

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Phase Diagram of the B-BN System at 5 GPa

机译：B-BN系统在5 GPa时的相图

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The chemical interaction and phase relations in the B-BN system have been in situ studied at 5 GPa and temperatures up to 2800 K using X-ray diffraction with synchrotron radiation. The thermodynamic analysis of the B-BN system based on experimental data allowed us to construct equilibrium and metastable phase diagrams of the system at 5 GPa. The only thermodynamically stable boron subnitride, B_(13)N2, melts incongruently at 2600 K and forms eutectic equilibrium with boron at 2300 K and 4 at. % of nitrogen.

机译：已经使用同步加速器辐射的X射线衍射技术在5 GPa和高达2800 K的温度下对B-BN系统中的化学相互作用和相关系进行了原位研究。根据实验数据对B-BN系统进行热力学分析，使我们能够构建5 GPa时该系统的平衡相和亚稳态相图。唯一的热力学稳定的亚氮化硼B_（13）N2在2600 K时融化并与硼在2300 K和4 at时形成共晶平衡。氮气百分比。

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《The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical》 |2010年第17期|共4页
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Vladimir L. Solozhenko; Oleksandr O. Kurakevych; Vladimir Z. Turkevich;
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Phase Diagram of the B-BN System at 5 GPa

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