Investigations of g-factor for Ti~(3+), V~(4+) and Cr~(5+) in anatase

Zhu L.; Wang M.

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Investigations of g-factor for Ti~(3+), V~(4+) and Cr~(5+) in anatase

机译：锐钛矿中Ti〜（3 +），V〜（4+）和Cr〜（5+）g因子的研究

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The g-factor formulas for d~1 ions in anatase are deduced from the Jahn-Teller effect and contributions of the charge transfer levels. The tetragonal distortions R∥-R_B (where R∥ and R_b denote the metal-ligand distances parallel with and perpendicular to the tetragonal axis) for Ti~(3+), V~(4+) and Cr~(5+) in anatase are studied to calculate the g-factors and the calculations are in good agreement with the experimental values. The distortions are much larger than the corresponding values in the pure crystal. The contributions of the charge transfer levels to g factors increase with the increasing valence state. It must be taken into account in the precise calculations of g factors for the high valence state d~1 ions in crystals.

机译：从Jahn-Teller效应和电荷转移能级的贡献推导了锐钛矿中d〜1离子的g因子公式。 Ti〜（3 +），V〜（4+）和Cr〜（5+）的四方畸变R∥-R_B（其中R∥和R_b表示平行于并垂直于四方轴的金属配体距离）研究了锐钛矿的g因子，计算结果与实验值吻合良好。失真比纯晶体中的相应值大得多。电荷转移能级对g因子的贡献随着价态的增加而增加。精确计算晶体中高价态d〜1离子的g因子时必须考虑到这一点。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第46期|共4页
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Zhu L.; Wang M.;
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正文语种 eng
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Experimental values; G factors; Pure crystals;

机译：实验值;G因子;纯晶体;

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1. Investigations of g-factor for Ti~(3+), V~(4+) and Cr~(5+) in anatase [J] . Zhu L., Wang M. Dalton transactions: An international journal of inorganic chemistry . 2013,第46期

机译：锐钛矿中Ti〜（3 +），V〜（4+）和Cr〜（5+）g因子的研究
2. Formation of High-Conductivity Regions in SnO_2- AO_x(A-Ti~(4+), Zr~(4+), Sb~(3+), Sb~(5+)) Films Exposed to UV Radiation or H_2 [J] . G.G.Postovalova, Y.E.Roginskaya Неорганические материалы . 2000,第4期

机译：在暴露于紫外线或H_2的SnO_2- AO_x（A-Ti〜（4+），Zr〜（4+），Sb〜（3+），Sb〜（5+））薄膜中形成高电导区
3. Formation of High-Conductivity Regions in SnO_2- AO_x(A-Ti~(4+), Zr~(4+), Sb~(3+), Sb~(5+)) Films Exposed to UV Radiation or H_2 [J] . G.G.Postovalova, Y.E.Roginskaya Неорганические материалы . 2000,第4期

机译：在 SnO_2- AO_x （A -Ti系〜（4+），锆〜（4+），锑〜（3+），锑〜（5 +））薄膜高导区的形成暴露于UV辐射或 H_2
4. The effect of Nb2O5 addition on the structural, dielectric and piezoelectric properties of Pb_(0,98)Ba_(0,02) (Zr_(0.52)Ti_(0.48))_(0,98)(Cr~(3+)_(0,5), Ta~(5+)_(0.5))_(0,02) ceramics [C] . Louanes Hamzioui, Fares Kahoul, Ahmed Boutarfaia International Conerence on Technologies and Materials for Renewable Energy, Environment and Sustainability . 2015

机译：Nb2O5添加对Pb_（0,98）Ba_（0,02）（Zr_（0.52）Ti_（0.48））_（0,98）（Cr〜（3+）的结构，电介质和压电性能的影响_（0.5），TA〜（5 +）_（0.5））_（0,02）陶瓷
5. Studies of crystalline paramagnetic holmium(3+), thulium(3+), and chromium(4+) lasers and Q-switches. [D] . Chen, Wei. 1995

机译：晶体顺磁性（3+），th（3+）和铬（4+）激光器和Q开关的研究。
6. Frequency of 5+/4+ Drinks as a Screener for Drug Use and Drug-Use Disorders [O] . Deborah A. Dawson, Wilson M. Compton, Bridget F. Grant -1

机译：5 + / 4 +饮料作为筛查毒品和毒品使用失调的频率
7. Alcaparrosaite, K_3Ti^(4+)Fe^(3+)(SO_4)_4O(H_2O)_2, a new hydrophobic Ti^(4+) sulfate from Alcaparrosa, Chile [O] . Kampf, A. R., Mills, S. J., Housley, R. M., 2012

机译：Alcaparrosaite，来自智利Alcaparrosa的新型疏水性Ti ^（4+）硫酸盐K_3Ti ^（4+）Fe ^（3 +）（SO_4）_4O（H_2O）_2
8. ПОСЛЕДОВАТЕЛЬНАЯ ИОНИЗАЦИЯ ПОЛОЖИТЕЛЬНЫХ ИОНОВ УГЛЕРОДА И АЗОТА ЭЛЕКТРОННЫМ УДАРОМ (С2+ → С3+ → С4+ → С5+ → С 6 + И N3+ → С4+ → N5+ → N6+ → N7+ ) [R] . Е.Д.Донец, В.И.Илющенко 1974

机译：通过电子碰撞顺序电离正碳离子和氮（C2 +→C3 +→C4 +→C5 +→C6 +和N3 +→C4 +→N5 +→N6 +→N7 +）

Investigations of g-factor for Ti~(3+), V~(4+) and Cr~(5+) in anatase

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