Impact of high π-density on the coordination properties of π-excess aromatic neutral σ~2P ligands - P(π)-donor bonds to Ag~+ and HgCl_2

Mohammed Ghalib; László K?ncz?l; László Nyulászi; Peter G. Jones; Gottfried J. Palm; Joachim W. Heinicke

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Impact of high π-density on the coordination properties of π-excess aromatic neutral σ~2P ligands - P(π)-donor bonds to Ag~+ and HgCl_2

机译：高π密度对π过量芳族中性σ〜2P配体-Ag（+）和HgCl_2的P（π）-供体键的配位性能的影响

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摘要

Unprecedented coordination types of non-zerovalent d~(10) transition metals (AgX, HgCl_2) by π-excess aromatic PvC ligands involving P(π)-donor bond contributions were detected by structural and quantum chemical studies.

机译：通过结构和量子化学研究，发现了由π-过量的芳香族PvC配体参与的非零价d〜（10）过渡金属（AgX，HgCl_2）前所未有的配位类型，涉及P（π）-给体键的贡献。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第1期|共4页
作者
Mohammed Ghalib; László K?ncz?l; László Nyulászi; Peter G. Jones; Gottfried J. Palm; Joachim W. Heinicke;
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正文语种 eng
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Impact; HgCl_2; coordination;

机译：冲击;HgCl_2;配位;

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1. Impact of high π-density on the coordination properties of π-excess aromatic neutral σ~2P ligands - P(π)-donor bonds to Ag~+ and HgCl_2 [J] . Mohammed Ghalib, László K?ncz?l, László Nyulászi, Dalton transactions: An international journal of inorganic chemistry . 2014,第1期

机译：高π密度对π过量芳族中性σ〜2P配体-Ag（+）和HgCl_2的P（π）-供体键的配位性能的影响
2. Al-H σ-bond coordination: expanded ring carbene adducts of AlH_3 as neutral bi- and tri-functional donor ligands [J] . Joseph A. B. Abdalla, Ian M. Riddlestone, Remi Tirfoin, Chemical Communications . 2013,第49期

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7. Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+and HgCl2 [O] . Mohammed Ghalib, László Könczöl, László Nyulászi, 2014

机译：高π密度对π-过量芳族空性σ2P配体 - P（π） - Donor键对Ag +和HgCl2的影响

Impact of high π-density on the coordination properties of π-excess aromatic neutral σ~2P ligands - P(π)-donor bonds to Ag~+ and HgCl_2

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