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首页> 外文期刊>Journal of Applied Polymer Science >Kinetic study of radical polymerization. II. Solid-state bulk polymerization of sodium methacrylate by differential scanning calorimetry
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Kinetic study of radical polymerization. II. Solid-state bulk polymerization of sodium methacrylate by differential scanning calorimetry

机译：自由基聚合的动力学研究。二。差示扫描量热法测定甲基丙烯酸钠的固态本体聚合

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The solid-state radical polymerization of sodium methacrylate was investigated. It was initiated by azobisisobutyronitrile, which was used as a radical initiator. Differential scanning calorimetry (DSC) was used to observe the endothermic and exothermic transitions during the polymerization reaction. Structural studies were performed with the DSC thermograms and Fourier transform infrared and ultraviolet-visible spectra, and all of the results confirmed the progress of the reaction. The obtained data revealed that the polymerization reaction proceeded completely with a 100% conversion. DeltaH of this reaction was calculated with various amounts of the initiator, and the peak temperatures were determined at different heating rates. The activation energy (19.7 kcal mol(-1)) was also obtained by the Kissinger method for this type of solid polymerization reaction. (C) 2003 Wiley Periodicals, Inc. [References: 24]
机译：研究了甲基丙烯酸钠的固态自由基聚合。它是由偶氮二异丁腈引发的，它被用作自由基引发剂。使用差示扫描量热法（DSC）观察聚合反应过程中的吸热和放热转变。用DSC热谱图和傅立叶变换的红外和紫外-可见光谱进行结构研究，所有结果证实了反应的进展。所得数据表明，聚合反应完全以100％的转化进行。用不同量的引发剂计算该反应的DeltaH，并在不同的加热速率下确定峰值温度。对于这种类型的固态聚合反应，还可以通过Kissinger方法获得活化能（19.7 kcal mol（-1））。 （C）2003 Wiley Periodicals，Inc. [参考：24]

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