首页> 外文期刊>Journal of Applied Polymer Science >Experimental and simulation studies on molecular transport of substituted monocyclic aromatic liquids into fluoropolymer sheet membranes: Liquid structure-diffusion, -sorption, and -permeation relationships
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Experimental and simulation studies on molecular transport of substituted monocyclic aromatic liquids into fluoropolymer sheet membranes: Liquid structure-diffusion, -sorption, and -permeation relationships

机译:取代单环芳族液体向含氟聚合物片状膜分子迁移的实验和模拟研究:液体结构-扩散,-吸附和-渗透关系

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摘要

The present study reports an investigation on the molecular transport of 10 monocyclic aromatic liquids (benzene, chlorobenzene, 1,2-dichlorobenzene, bromobenzene, toluene, p-xylene, trimethylbenzene, ethylbenzene, methoxybenzene, and ethoxybenzene) at 40 and 50degreesC through sheet polymeric membranes (FLS-2650) using a sorption gravimetric technique. Diffusion and permeation coefficients of these liquids were calculated from the sorption data using Fick's diffusion equation. Sorption results were analyzed typically in the case of benzene and chlorobenzene to compute the concentration profiles at different depths along the thickness direction of the sheet membranes and at different time intervals by solving the Fick's equation under appropriate boundary conditions, based on the numerical simulation method developed in "C" language using a finite-difference method. Transport results were analyzed to establish the relationships between the penetrating liquid structures with diffusion, permeation, and sorption data. (C) 2004 Wiley Periodicals, Inc. [References: 17]
机译:本研究报告了在40和50°C下通过片状聚合物对10种单环芳族液体(苯,氯苯,1,2-二氯苯,溴苯,甲苯,对二甲苯,三甲基苯,乙苯,甲氧基苯和乙氧基苯)的分子传输的研究。膜(FLS-2650)使用吸附重量技术。这些液体的扩散系数和渗透系数是使用Fick扩散方程根据吸附数据计算得出的。通常,在苯和氯苯的情况下,通过在适当的边界条件下求解Fick方程,通过分析Fick方程,分析苯和氯苯的吸附结果,以计算沿膜厚度方向不同深度和不同时间间隔的浓度分布。在C语言中使用有限差分法。分析传输结果以建立渗透性液体结构与扩散,渗透和吸附数据之间的关系。 (C)2004 Wiley Periodicals,Inc. [参考:17]

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