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Synthesis and application of an anionic water-soluble copolymer as a dispersant for barium titanate slurries

机译:阴离子型水溶性共聚物作为钛酸钡浆液分散剂的合成与应用

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摘要

An anionic water-soluble copolymer, poly(acrylamide/4-carboxylamino-4-oxo-2-butenate) (PAAM/COB), was synthesized and used as a dispersion agent for BaTiO3 particles. PAAM/COB was prepared from acrylamide and 4-carboxylamino-4-oxo-2-butenate in basic conditions through free-radical polymerization. The structure of this copolymer was verified by IR and H-1-NMR spectra. We examined the dispersion effects of PAAM/COB by measuring the viscosity and sedimentation of BaTiO3 suspensions and by analyzing the particle sizes. The results indicate that this copolymer was indeed effective in dispersing the particles, for the resulting suspensions were less viscous, more stabilized, and contained powder with smaller particle sizes. (c) 2005 Wiley Periodicals, Inc.
机译:合成了一种阴离子水溶性共聚物,聚(丙烯酰胺/ 4-羧基氨基-4-氧代-2-丁烯酸酯)(PAAM / COB),并用作BaTiO3颗粒的分散剂。 PAAM / COB是在碱性条件下通过自由基聚合反应由丙烯酰胺和4-羧基氨基-4-氧代-2-丁烯酸酯制得的。该共聚物的结构通过IR和H-1-NMR光谱验证。我们通过测量BaTiO3悬浮液的粘度和沉降并分析粒度来检查PAAM / COB的分散效果。结果表明,该共聚物的确确实有效地分散了颗粒,因为所得的悬浮液粘度较小,稳定性更高,并且所含粉末的粒径较小。 (c)2005年Wiley Periodicals,Inc.

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