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Cure Behavior of epoxy resin containing castor oil and cashew nut shell liquid and its derivative

机译:含蓖麻油和腰果壳液及其衍生物的环氧树脂的固化行为

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The cure behavior of epoxy resin with a conventional amide-type hardener (HD) was investigated in the presence of castor oil (CO), cashew nut shell liquid (CNSL), and cashew nut shell liquid-formaldehyde resin (CFR) with dynamic differential scanning calorimetry (DSC). The activation energy of the curing reaction was also calculated on the basis of nonisothermal DSC thermograms at various heating rates. A one-stage curing was noted in the case of epoxy resin filled with CO, whereas the epoxy resin with CNSL and CFR showed a two-stage curing process. A competitive cure reaction was noted for the epoxy resin/CNSL(or CFR)/HD blends. In the absence of HD, CFR showed lower values of curing enthalpy than that of CNSL. The activation energy of epoxy resin curing increased with increasing CNSL and CFR loading. (c) 2007 Wiley Periodicals, Inc.
机译:在蓖麻油(CO),腰果壳液(CNSL)和腰果壳液-甲醛树脂(CFR)存在动态差的情况下,研究了使用常规酰胺型固化剂(HD)的环氧树脂的固化行为。扫描量热法(DSC)。还基于在不同加热速率下的非等温DSC热分析图计算了固化反应的活化能。在填充有CO的环氧树脂的情况下,注意到了一个阶段的固化,而具有CNSL和CFR的环氧树脂则显示了一个两阶段的固化过程。注意到环氧树脂/ CNSL(或CFR)/ HD混合物的竞争性固化反应。在没有HD的情况下,CFR的固化焓值低于CNSL。环氧树脂固化的活化能随CNSL和CFR含量的增加而增加。 (c)2007年Wiley Periodicals,Inc.

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