• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Polymer Science >Synthesis of a novel polymerizable surfactant and its application in the emulsion polymerization of vinyl acetate, butyl acrylate, veova 10, and hexafluorobutyl methacrylate
【24h】

Synthesis of a novel polymerizable surfactant and its application in the emulsion polymerization of vinyl acetate, butyl acrylate, veova 10, and hexafluorobutyl methacrylate

机译：新型可聚合表面活性剂的合成及其在乙酸乙烯酯，丙烯酸丁酯，veova 10和甲基丙烯酸六氟丁酯的乳液聚合中的应用

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A novel anionic, polymerizable fumaric surfactant (surfmer) was synthesized. The chemical structure of the surfactant was confirmed with H-1-NMR, IR, and mass spectrometry. The surfmer was then used with constant addition profiles in the semicontinuous polymerization of vinyl acetate, butyl acrylate, Veova 10, and hexafluorobutyl methacrylate. The particle size, amount of coagulum, and stability against electrolytes and freezing/thawing were evaluated. Films were cast from latices; then, photographs were taken of the films after immersion in water for days, and the water adsorption was assessed. As a reference, an unreactive surfactant (sodium dodecyl sulfate) was also used for the polymerization. Compared with sodium dodecyl sulfate, the surfmer behaved much better with respect to the stability of the latices and the water sensitivity of the films. (C) 2007 Wiley Periodicals, Inc.
机译：合成了一种新型的阴离子型可聚合富马酸表面活性剂（表面活性剂）。表面活性剂的化学结构通过H-1-NMR，IR和质谱确定。然后将表面活性剂以恒定的加料曲线用于乙酸乙烯酯，丙烯酸丁酯，Veova 10和甲基丙烯酸六氟丁酯的半连续聚合中。评价了粒径，凝结物的量以及对电解质和冷冻/融化的稳定性。电影是用胶乳铸成的;然后，将其浸入水中数天后拍摄照片，并评估吸水率。作为参考，未反应的表面活性剂（十二烷基硫酸钠）也用于聚合。与十二烷基硫酸钠相比，该表面活性剂在胶乳的稳定性和薄膜的水敏感性方面表现更好。 （C）2007 Wiley期刊公司

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号