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Distribution of morphology and transport properties of water vapor in injection-molded biodegradable aliphatic polyester

机译:注射成型可生物降解脂肪族聚酯中水蒸气的形态分布和传输特性

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摘要

A biodegradable polyester, poly(tetra-methylene dodecanedioate), was injection molded in a rectangular cavity. Thin sections were sliced from molded samples starting from the skin. The morphology distribution inside the molded samples was studied by X-ray analysis. The diffusion and solubility coefficient of water vapor were then measured using the microgravimetric method at the temperature of 30°C. Results show that morphology developed during the process influences the diffusion of water molecules through the polymer matrix. In particular, a direct influence of crystalline degree on the sorption and diffusion parameters was identified.
机译:将可生物降解的聚酯聚四亚甲基十二烷二酸酯注射成型在一个矩形腔中。从皮肤开始,从模制样品上切下薄片。通过X射线分析研究了模制样品内部的形态分布。然后在30℃的温度下使用微重力法测量水蒸气的扩散和溶解度系数。结果表明,在此过程中形成的形态会影响水分子通过聚合物基质的扩散。特别地,确定了结晶度对吸附和扩散参数的直接影响。

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