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Optimization of Thermoelectric Properties of Metal-Oxide-Based Polymer Composites

机译:金属氧化物基聚合物复合材料热电性能的优化

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摘要

Thermoelectric modules can be used for thermal energy harvesting. Common rigid thermoelectric stacks usually contain heavy metal alloys such as Bi_2Te_3. In order to substitute conventional materials and to reduce manufacturing costs, nontoxic, inexpensive and abundant materials using low-cost processes are first choice. This study deals with polymer composites consisting of a polysiloxane matrix filled with thermoelectric Sn_(0.85)Sb_(0.15)O_2 particles in micrometer scale. Thin composite sheets have been prepared by doctor blade technique and the Seebeck coefficient, the electrical and thermal conductivity, and the porosity were measured. Platelet-type particles, consisting of Sn0.85Sb0.15O2-coated insulating mica substrate and globular Sn_(0.85)Sb_(0.15)O_2 particles have been varied in size, coating thickness and were mixed with each other in different ratios. The filler content was varied in order to maximize the figure of merit, ZT, to 1.9 × 10~(-5)±4 × 10~(-6). Owing to their low raw material costs and the high degree of design freedom of polymer composites, one may use these materials in thermoelectric generators for remote low-power demanding applications.
机译:热电模块可用于热能收集。普通的刚性热电堆通常包含重金属合金,例如Bi_2Te_3。为了替代常规材料并降低制造成本,使用低成本工艺的无毒,廉价和丰富的材料是首选。这项研究涉及由聚硅氧烷基质组成的聚合物复合材料,该基质填充了微米级的热电Sn_(0.85)Sb_(0.15)O_2颗粒。已经通过刮刀技术制备了复合薄片,并测量了塞贝克系数,电导率和导热率以及孔隙率。由Sn0.85Sb0.15O2包覆的绝缘云母基底和球形Sn_(0.85)Sb_(0.15)O_2颗粒组成的血小板型颗粒的大小,涂层厚度不同,并且以不同的比例相互混合。改变填料含量以使品质因数ZT最大,为1.9×10〜(-5)±4×10〜(-6)。由于其低的原材料成本和聚合物复合材料的高度设计自由度,人们可以将这些材料用于热电发电机中,以用于要求低功率的远程应用。

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