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首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >In-situ hydrothermal synthesis of three-dimensional Mn0_2-CNT nanocompositesand their electrochemical properties
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In-situ hydrothermal synthesis of three-dimensional Mn0_2-CNT nanocompositesand their electrochemical properties

机译:三维Mn0_2-CNT纳米复合材料的原位水热合成及其电化学性能

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摘要

Three-dimensional (3-D) Mn0_2-carbon nanotube (CNT) nanocomposites were prepared by a simple one-pot hydrothermal method. An electrode was then prepared with these nanocomposites. For comparativeinvestigation, Mn0_2 microspheres were also hydrothermally prepared without adding CNTs. The as-synthesized Mn0_2 microspheres were then mechanically mixed with CNTs to prepare a subsequentelectrode. The samples were characterized by electron microscopy, X-ray diffraction, and electrochemi-cal methods. It has been revealed that a 3-D conductive network of CNTs was formed with microspheresof Mn0_2 nanorods interwoven with and connected by CNTs. As a result, the hydrothermally mixed Mn0_2-CNT electrode showed a higher specific capacitance than the mechanically mixed electrode. Ithas therefore been concluded that the hydrothermal mixing method yields a more homogeneous prod-uct that is better suited to take full advantages of both the high capacitance of Mn0_2and the high electricalconductivity of CNTs. The 3-D Mn0_2-CNT nanocomposites reported herein have provided a promisingelectrode material for supercapacitors and other electrochemical energy storage/conversion devices.
机译:通过简单的一锅水热法制备了三维(3-D)Mn0_2-碳纳米管(CNT)纳米复合材料。然后用这些纳米复合材料制备电极。为了进行比较研究,在不添加碳纳米管的情况下,水热制备了Mn0_2微球。然后将合成后的Mn0_2微球与CNT机械混合以制备后续电极。通过电子显微镜,X射线衍射和电化学方法对样品进行表征。已经发现,由Mn0_2纳米棒的微球与CNT交织并连接而形成的CNT的3-D导电网络。结果,水热混合的Mn0_2-CNT电极显示出比机械混合的电极更高的比电容。因此可以得出结论,水热混合法产生的产物更加均匀,更适合充分利用Mn0_2的高电容和CNTs的高电导率的全部优势。本文报道的3-D MnO_2-CNT纳米复合材料为超级电容器和其他电化学能量存储/转换装置提供了有希望的电极材料。

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