Rate Constants for the Reactions of OH Radicals with Fluorinated Ethenes: Kinetic Measurements and Correlation between Structure and Reactivity

Kazuaki Tokuhashi; Kenji Takizawa; Shigeo Kondo

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Rate Constants for the Reactions of OH Radicals with Fluorinated Ethenes: Kinetic Measurements and Correlation between Structure and Reactivity

机译：用氟化醚的OH基团反应的速率常数：动力学测量和结构与反应性之间的相关性

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机译：<！[CDATA [CDATA [oh基团的速率常数用四种氟化醚（CF_（2）= CHF，（

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2018年第19期|共8页
作者
Kazuaki Tokuhashi; Kenji Takizawa; Shigeo Kondo;
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作者单位

National Institute of Advanced Industrial Science and Technology (AIST) 1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan;

National Institute of Advanced Industrial Science and Technology (AIST) 1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan;

National Institute of Advanced Industrial Science and Technology (AIST) 1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Rate Constants for the Reactions of OH Radicals with Fluorinated Ethenes: Kinetic Measurements and Correlation between Structure and Reactivity (vol 122, pg 4593, 2018) [J] . Tokuhashi Kazuaki, Takizawa Kenji, Kondo Shigeo The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2019,第1期

机译：用氟化醚的OH基团反应的速率常数：动力学测量和结构与反应性之间的相关性（Vol 122，PG 4593,2018）
2. Competition kinetics using the UV/H_2O_2 process: a structure reactivity correlation for the rate constants of hydroxyl radicals toward nitroaromatic compounds [J] . Fernando S. Garcia Einschlag, Luciano Carlos, Alberto L. Capparelli Chemosphere . 2003,第1期

机译：使用UV / H_2O_2过程的竞争动力学：羟基自由基对硝基芳族化合物的速率常数的结构反应性相关性
3. REACTIVITY OF RADICAL CATIONS - EFFECT OF RADICAL CATION AND ALKENE STRUCTURE ON THE ABSOLUTE RATE CONSTANTS OF RADICAL CATION MEDIATED CYCLOADDITION REACTIONS [J] . Schepp NP, Johnston LJ Journal of the American Chemical Society . 1996,第12期

机译：自由基的反应性-自由基和烯烃结构对自由基介导的荷载反应绝对速率常数的影响。
4. REACTIVITY-STRUCTURE BASED RATE ESTIMATION RULES FOR ALKYL RADICAL H- ATOM SHIFT AND ALKENYL RADICAL CYCLOADDITION REACTIONS [C] . Kun Wang, Stephanie M. Villano, Anthony M. Dean ACS National Meeting Exhibition . 2015

机译：基于反应性结构的烷基自由基H-原子移位和链烯基环加成反应的速率估计规则
5. MECHANISTIC STUDIES OF THE S(RN)1 MECHANISM FOR AROMATIC SUBSTITUTION: 1. SPECTROSCOPY AND KINETICS OF ELECTRON CAPTURE BY AROMATIC SUBSTRATES, 2. ABSOLUTE RATE CONSTANTS FOR REACTIONS OF PHENYL RADICAL WITH NUCLEOPHILES (RADICAL ANIONS) [D] . HERR, DANIEL JOSEPH CHRISTIAN. 1984

机译：芳香取代的S（RN）1机理的机理研究：1.芳香族底物的电子捕获光谱和动力学，2.苯自由基与核素（自由基）反应的绝对速率常数。
6. Reversible Hydrogen Transfer Reactions in Thiyl Radicals From Cysteine and Related Molecules: Absolute Kinetics and Equilibrium Constants Determined by Pulse Radiolysis [O] . Thomas Nauser, Willem H. Koppenol, Christian Schöneich -1

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7. Correction to “Rate Constants for the Reactions of OH Radicals with Fluorinated Ethenes: Kinetic Measurements and Correlation between Structure and Reactivity” [O] . Kazuaki Tokuhashi, Kenji Takizawa, Shigeo Kondo 2018

机译：校正“用氟化醚的OH基团反应的速率常数：动力学测量和结构与反应性之间的相关性”
8. Temperature-Dependent Rate Constants and Substituent Effects for the Reactions of Hydroxyl Radicals with Three Partially Fluorinated Ethers [R] . Hsu, K. J. , DeMore, W. B. 1995

机译：羟基自由基与三种部分氟化醚反应的温度依赖性速率常数和取代基效应

Rate Constants for the Reactions of OH Radicals with Fluorinated Ethenes: Kinetic Measurements and Correlation between Structure and Reactivity

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