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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures
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A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

机译:一种富含氮的配体,作为基于镝的0D和1D架构的缓慢磁性松弛的支架

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摘要

A recently designed nitrogen-rich ligand is successfully applied as a scaffold for lanthanide ions to show that the intricate chemistry of energetic materials can be combined with other fields of research, including that of molecular magnetism. Herein, we report the synthesis of two different types of molecular architectures using a single ligand template, in which the discrete monomer exhibits single-molecule magnet-like behaviour along with two well-isolated modes of magnetic relaxation.
机译:最近设计的富含氮配体的成功用作镧系元素离子的支架,以表明,能量材料的复杂化学可以与其他研究领域结合,包括分子磁性。 这里,我们使用单个配体模板报告两种不同类型的分子架构,其中离散单体表现出单分子磁体样行为以及两个良好的磁性松弛模式。

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