Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra

Tang Mingjing; Iyer Abishek K.; Zhang Dong; Yin Wenlong; Mar Arthur

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Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra

机译：含硫化硫化物Ba5cd2ga2s10含有边缘和角落分享四面体链条的链条

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The quaternary sulfide Ba5Cd2Ga2S10 was prepared by reaction of BaS, CdS, and Ga2S3 at high temperatures. Single-crystal X-ray diffraction analysis revealed that it adopts a new orthorhombic structure type (space group Pccn, Z = 4, a = 12.7664(7) angstrom, b = 12.8060(7) angstrom, c = 12.1265(7) angstrom) consisting of one-dimensional anionic chains [CdGaS5](5-) built from edge- and corner-sharing tetrahedra centred by Cd and Ga atoms in an ordered fashion, with Ba2+ cations located between the chains. The UV-vis-NIR diffuse reflectance spectrum reveals two optical transitions at 1.92(2) and 3.29(2) eV, the latter being consistent with the yellow colour of the crystals. (C) 2018 Elsevier B.V. All rights reserved.

机译：通过在高温下通过BAS，CD和GA2S3反应制备季硫化物BA5CD2GA2S10。单晶X射线衍射分析显示，它采用新的正交结构型（空间组PCCN，Z = 4，A = 12.7664（7）埃，B = 12.8060（7）Angstrom，C = 12.1265（7）埃）由一维阴离子链[CDGAS5]（5-）由由CD和GA原子以有序方式为中心的边缘和角落共用四面体构建，Ba2 +位于链之间的阳离子。 UV-Vis-Nir漫反射谱谱显示出1.92（2）和3.29（2）EV的两个光学转变，后者与晶体的黄色一致。（c）2018年elestvier b.v.保留所有权利。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2018年第2018期|共5页
作者
Tang Mingjing; Iyer Abishek K.; Zhang Dong; Yin Wenlong; Mar Arthur;
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作者单位

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Peoples R China;

Univ Alberta Dept Chem Edmonton AB T6G 2G2 Canada;

Univ Alberta Dept Chem Edmonton AB T6G 2G2 Canada;

China Acad Engn Phys Inst Chem Mat Mianyang 621900 Peoples R China;

Univ Alberta Dept Chem Edmonton AB T6G 2G2 Canada;

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原文格式 PDF
正文语种 eng
中图分类合金学与各种性质合金;金属材料;
关键词
semiconductors; crystal structure; Optical properties;

机译：半导体;晶体结构;光学性质;

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1. Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra [J] . Tang Mingjing, Iyer Abishek K., Zhang Dong, Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2018,第期

机译：含硫化硫化物Ba5cd2ga2s10含有边缘和角落分享四面体链条的链条
2. Synthesis and crystal structure of Li_2[(UO_2)(MoO_4)_2], a uranyl molybdate with chains of corner-sharing uranyl square bipyramids and MoO_4 tetrahedra [J] . Sergey V. Krivovichev, Peter C. Burns Solid state sciences . 2003,第3期

机译：Li_2 [（UO_2）（MoO_4）_2]，一种具有角共享铀酰方形双锥体和MoO_4四面体的链的钼酸铀酰的合成和晶体结构
3. Hubbard chains network on corner-sharing tetrahedra: Origin of the heavy-fermion state in LiV2O4 - art. no. 155108 [J] . Fujimoto S. Physical Review, B. Condensed Matter . 2002,第15期

机译：角共享四面体上的哈伯德链网络：LiV2O4中重费米子状态的起源-艺术。没有。 155108
4. Design of New Structural Types from Oxocentered Tetrahedra: Continuous Polycationic Series from 1D Chains to 2D Planes in New Bismuth Compounds [C] . Olivier Mentre, Marie Colmont, Marielle Huve Materials Research Society Symposium on Solid-State Chemistry of Inorganic Materials . 2006

机译：来自obocentered tetrahedra的新结构类型的设计：从1d链到新的铋化合物的连续聚阳离子系列到2D平面
5. Ba4KFe3O9: A Novel Ferrite Containing Discrete Six-member Rings of Corner-sharing FeO4 Tetrahedra [O] . Qingbiao Zhao, Saritha Nellutla, Won-Joon Son, -1

机译：Ba4KFe3O9：一种新型铁氧体含角共享FeO4四面体的离散六元环
6. Hubbard chains network on corner-sharing tetrahedra: Origin of the heavy-fermion state in LiV2O4 [O] . Fujimoto S 2002

机译：角共享四面体上的哈伯德链网络：LiV2O4中重费米子状态的起源

Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra

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