Mn-MIL-100 heterogeneous catalyst for the selective oxidative cleavage of alkenes to aldehydes

Ha Ying; Mu Manman; Liu Qingling; Ji Na; Song Chunfeng; Ma Degang

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Mn-MIL-100 heterogeneous catalyst for the selective oxidative cleavage of alkenes to aldehydes

机译：Mn-MIL-100用于烯烃的选择性氧化切割的非均相催化剂

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Four MIL metal organic framework materials with large surface area and high stability were utilized as heterogeneous catalysts in the selective oxidation of styrene with tert-butylhydroperoxide (70% aqueous) as an oxidant in acetonitrile. Mn-MIL-100 exhibits excellent styrene conversion (89%) and benzaldehyde selectivity (85%) under optimized conditions. Furthermore, Mn-MIL-100 displays superior catalytic activity in the selective oxidation of aryl-olefins and is reused at least three times without significant deactivation. It appears that this specific material would open up a new pathway for MOFs towards the selective catalytic oxidation of aryl-olefins to the corresponding aldehydes.

机译：具有大表面积和高稳定性的四个米尔金属有机框架材料用作在苯乙烯的苯乙烯（70％水溶液）中选择性氧化作为乙腈中的氧化剂的非均相催化剂。 Mn-MIL-100在优化条件下表现出优异的苯乙烯转化（89％）和苯甲醛选择性（85％）。此外，Mn-MIL-100在芳基烯烃的选择性氧化中显示出优异的催化活性，并且在没有显着去激活的情况下重复使用至少三次。似乎这种特定材料将使MOF朝向相应的醛的选择性催化氧化的MOF为MOF开辟新的途径。

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来源
《Catalysis Communications》 |2018年第2018期|共5页
作者
Ha Ying; Mu Manman; Liu Qingling; Ji Na; Song Chunfeng; Ma Degang;
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作者单位

Tianjin Univ Sch Environm Sci &

Engn Tianjin Key Lab Indoor Air Environm Qual Control 135 Yaguan Rd Haihe Educ Pk Tianjin 300350 Peoples R China;

Tianjin Univ Sch Sci 135 Yaguan Rd Haihe Educ Pk Tianjin 300350 Peoples R China;

Tianjin Univ Sch Environm Sci &

Engn Tianjin Key Lab Indoor Air Environm Qual Control 135 Yaguan Rd Haihe Educ Pk Tianjin 300350 Peoples R China;

Tianjin Univ Sch Environm Sci &

Engn Tianjin Key Lab Indoor Air Environm Qual Control 135 Yaguan Rd Haihe Educ Pk Tianjin 300350 Peoples R China;

Tianjin Univ Sch Environm Sci &

Engn Tianjin Key Lab Indoor Air Environm Qual Control 135 Yaguan Rd Haihe Educ Pk Tianjin 300350 Peoples R China;

Tianjin Univ Sch Environm Sci &

Engn Tianjin Key Lab Indoor Air Environm Qual Control 135 Yaguan Rd Haihe Educ Pk Tianjin 300350 Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
MOFs; Mn-MIL-100; Selective oxidation; Styrene; Benzaldehyde;

机译：MOFS;MN-MIL-100;选择性氧化;苯乙烯;苯甲醛;

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专利

1. Mn-MIL-100 heterogeneous catalyst for the selective oxidative cleavage of alkenes to aldehydes [J] . Ha Ying, Mu Manman, Liu Qingling, Catalysis Communications . 2018,第期

机译：Mn-MIL-100用于烯烃的选择性氧化切割的非均相催化剂
2. Selective Catalytic Oxidation of Alcohols, Aldehydes, Alkanes and Alkenes Employing Manganese Catalysts and Hydrogen Peroxide [J] . Pattama Saisaha, Lea Buettner, Margarethe van der Meer Advanced synthesis & catalysis . 2013,第13期

机译：使用锰催化剂和过氧化氢的醇，醛，烷烃和烯烃的选择性催化氧化
3. Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO_2-Supported Ru-Monomer Complex Catalyst [J] . Mizuki Tada, Satoshi Muratsugu, Mutsuo Kinoshita, Journal of the American Chemical Society . 2010,第2期

机译：SiO_2负载Ru单体配合物催化剂上醛氧化和烯烃环氧化的选择性氧化途径。
4. Jacobsen catalyst anchored onto modified carbon xerogel as enantioselective heterogeneous catalysts for alkene epoxidation [C] . International carbon conference . 2006

机译：jacobsen催化剂固定在改性碳Xerogel上作为烯烃环氧化的映选择性非均相催化剂
5. Design of Nanostructured Silver Catalysts for Selective Heterogeneous Catalytic and Photocatalytic Oxidation Reactions. [D] . Christopher, Phillip Neil. 2011

机译：用于选择性非均相催化和光催化氧化反应的纳米银催化剂的设计。
6. Fast and Green Microwave-Assisted Conversion of Essential Oil Allylbenzenes into the Corresponding Aldehydes via Alkene Isomerization and Subsequent Potassium Permanganate Promoted Oxidative Alkene Group Cleavage [O] . Thi Xuan Thi Luu, Trinh To Lam, Thach Ngoc Le, 2009

机译：通过烯异构化和随后的高锰酸钾促进氧化烯基裂解快速绿色微波辅助将香精油烯丙基苯转化为相应的醛
7. Selective Catalytic Oxidation of Alcohols, Aldehydes, Alkanes and Alkenes Employing Manganese Catalysts and Hydrogen Peroxide [O] . Saisaha Pattama, Buettner Lea, van der Meer Margarethe, 2013

机译：使用锰催化剂和过氧化氢的醇，醛，烷烃和烯烃的选择性催化氧化

Mn-MIL-100 heterogeneous catalyst for the selective oxidative cleavage of alkenes to aldehydes

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