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首页> 外文期刊>Catalysis Communications >Transition metal-free and base-mediated transformation arylation of unactivated benzene with aryl halides in presence of N,N '-bis(salicylidene) ethylenediamine as organocatalyst
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Transition metal-free and base-mediated transformation arylation of unactivated benzene with aryl halides in presence of N,N '-bis(salicylidene) ethylenediamine as organocatalyst

机译:在N,N'-BIS(水杨烯)乙二胺作为有机催化剂存在下,无催化苯的无催化苯的无致活化苯的转化芳族

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摘要

Direct transition metal-free arylation of benzene has been achieved using a combination of various aryl halides and N,N'-bis(salicylidene)ethylenediamine as a new ligand and catalyst. This facile one-pot reaction is reported as a new C-H functionalization protocol for the synthesis of biaryls. In this research, 18-crown-6 and several Schiff-bases were tested and among them, N,N'-bis(salicylidene)ethylenediamine was found to be a great catalyst for this cross-coupling.
机译:使用各种芳基卤化物和N,N'-BIS(水杨酸)乙二胺作为新配体和催化剂,实现了直接过渡无金属芳基苯的苯。 将该容易的单壶反应报告为合成前列的新型C-H官能化方案。 在本研究中,测试了18冠-6和几个席夫碱,其中N,N'-BIS(水杨烯)乙二胺被发现是该交叉偶联的巨大催化剂。

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