Coordination-induced assembly of coordination polymer submicrospheres: Promising antibacterial and in vitro anticancer activities

Wang K.; Ma X.; Shao D.; Geng Z.; Zhang Z.; Wang Z.

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Coordination-induced assembly of coordination polymer submicrospheres: Promising antibacterial and in vitro anticancer activities

机译：配位聚合物亚微球的配位诱导组装：有望的抗菌和体外抗癌活性

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Spheres-like coordination polymer architectures in submicro regimes have been synthesized from the hydrothermal reaction of transition metal ions and 3,5-bis(pyridin-3-ylmethylamino)benzoic acid (L1). The size of the final coordination polymer was dependent on the concentrations of reactants. Scanning electron microscopy studies monitored at numerous stages of growth reveal that coordination-induced morphology changes from uncoordinated flowerlike ligands to sphere-like coordination polymer particles. Moreover, variations of luminescent and antibacterial profiles are associated with coordination environments or the size of as-obtained coordination polymer samples. In addition, the newly synthesized Cu-based polymer particles may act as novel metal-based anticancer drugs in the future because of their potent in vitro anticancer activities against three chosen cancer lines MCF-7, HeLa, and NCI-H446.

机译：通过过渡金属离子与3,5-双（吡啶-3-基甲基氨基）苯甲酸（L1）的水热反应，合成了亚微米级的球状配位聚合物结构。最终配位聚合物的尺寸取决于反应物的浓度。在生长的多个阶段进行监测的扫描电子显微镜研究表明，配位诱导的形态从未配位的花状配体变为球形的配位聚合物颗粒。此外，发光和抗菌曲线的变化与配位环境或配位聚合物样品的大小有关。另外，由于新合成的基于铜的聚合物颗粒针对三种选择的癌系MCF-7，HeLa和NCI-H446的有效体外抗癌活性，它们将来可能会成为新型的基于金属的抗癌药物。

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《Crystal growth & design》 |2012年第7期|共6页
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Wang K.; Ma X.; Shao D.; Geng Z.; Zhang Z.; Wang Z.;
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1. Coordination-induced assembly of coordination polymer submicrospheres: Promising antibacterial and in vitro anticancer activities [J] . Wang K., Ma X., Shao D., Crystal growth & design . 2012,第7期

机译：配位聚合物亚微球的配位诱导组装：有望的抗菌和体外抗癌活性
2. Synthesis and structure of a 1-D copper(II) coordination polymer bridged both by oxamido and carboxylate: in vitro anticancer activity and reactivity toward DNA and protein BSA [J] . Li Xue-Jie, Zheng Kang, Li Yan-Tuan, Journal of Coordination Chemistry . 2015,第5a6期

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4. Synthesis, Crystal Structure and Antibacterial Activity of 1D Chain Ca(II) Coordination Polymer [C] . Xi-Shi Tai International Conference on Material Engineering, Chemistry, Bioinformatics . 2011

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Coordination-induced assembly of coordination polymer submicrospheres: Promising antibacterial and in vitro anticancer activities

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