High Proton Conduction in Two Co-II and Mn-II Anionic Metal-Organic Frameworks Derived from 1,3,5-Benzenetricarboxylic Acid

Liu Sui-Jun; Cao Chen; Yang Fan; Yu Mei-Hui; Yao Shu-Li; Zheng Teng-Fei; He Wei-Wei; Zhao Hai-Xia; Hu Tong-Liang; Bu Xian-He

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High Proton Conduction in Two Co-II and Mn-II Anionic Metal-Organic Frameworks Derived from 1,3,5-Benzenetricarboxylic Acid

机译：1,3,5-苯三羧酸衍生的两个Co-II和Mn-II阴离子金属有机骨架中的高质子传导

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Isostructural Coll and Mnll organic frameworks with anionic frameworks and counterions (Me2NH2)(+), namely {[M2Cl2(BTC)(4/3)]center dot(Me2NH2)(+)(2)center dot 4/3H(2)O} (M = Co (1) and Mn (2)), have been constructed by one-pot synthesis. Complexes 1 and 2 take paddlewheel -like dinuclear metal cluster-based three-dimensional structures. Thermogravimetric analysis and variable-temperature powder X-ray diffraction spectra suggested that 1 displays better thermal stability than 2. Both exhibit relatively high proton conductivities at 65% relative humidity (RH) and room temperature (sigma > 2.5 X 10(-4) S cm(-1)); however, complex 1 possesses the better cycling capability and stability with E-a = 0.21 eV under 65% RH.

机译：具有阴离子骨架和抗衡离子（Me2NH2）（+）的同构Coll和Mnll有机骨架，即{[M2Cl2（BTC）（4/3）]中心点（Me2NH2）（+）（2）中心点4 / 3H（2） O}（M = Co（1）和Mn（2）），是通过一锅法合成的。配合物1和2采用桨轮状双核金属簇为基础的三维结构。热重分析和可变温度粉末X射线衍射光谱表明，1表现出比2更好的热稳定性。两者在相对湿度（RH）和室温为65％时均表现出较高的质子电导率（sigma> 2.5 X 10（-4）S厘米（-1））;但是，配合物1具有更好的循环能力和稳定性，在65％RH下E-a = 0.21 eV。

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《Crystal growth & design》 |2016年第12期|共5页
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Liu Sui-Jun; Cao Chen; Yang Fan; Yu Mei-Hui; Yao Shu-Li; Zheng Teng-Fei; He Wei-Wei; Zhao Hai-Xia; Hu Tong-Liang; Bu Xian-He;
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1. High Proton Conduction in Two Co-II and Mn-II Anionic Metal-Organic Frameworks Derived from 1,3,5-Benzenetricarboxylic Acid [J] . Liu Sui-Jun, Cao Chen, Yang Fan, Crystal growth & design . 2016,第12期

机译：1,3,5-苯三羧酸衍生的两个Co-II和Mn-II阴离子金属有机骨架中的高质子传导
2. Network-Selectivity, Magnetism, and Proton Conduction of 2-D and 3-D Metal-Organic Frameworks of the Constituents {P(CH2OH)(4)}(+)/M-II (Mn-II, Fe-II, or Co-II)/[Cr-III(ox)(3)](3-) [J] . Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第1期

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3. trans-STEREOSELECTIVE CATALYSIS OF THE HENRY REACTION BY A NEW METAL-ORGANIC FRAMEWORK OF IRON(HI) WITH 1,3,5-BENZENETRICARBOXYLIC ACID [J] . S. A. Sotnik, I. L. Eremenko, V. V. Pavlishchuk Theoretical and Experimental Chemistry . 2013,第2期

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4. The Study and Characterization of a Novel Structure of 1,3,5-Benzenetricarboxylic Acid [C] . HaiYan Tan, Cheng Liu, JinPing Wu International Conference on Material Engineering, Chemistry, Bioinformatics . 2014

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5. Metal-Organic Frameworks: A New Class of Materials for Anhydrous Proton Conduction [D] . Hurd, Jeff Allen 2010

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High Proton Conduction in Two Co-II and Mn-II Anionic Metal-Organic Frameworks Derived from 1,3,5-Benzenetricarboxylic Acid

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