Mineral-Inspired Crystal Growth and Physical Properties Na2Cu(SO4)(2) and Review of Na2M(SO4)(2)(H2O)(x) (x=0-6) Compounds

Kovrugin Vadim M.; Nekrasova Diana O.; Siidra Oleg I.; Mentre Olivier; Masquelier Christian; Stefanovich Sergey Yu.; Colmont Marie

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Mineral-Inspired Crystal Growth and Physical Properties Na2Cu(SO4)(2) and Review of Na2M(SO4)(2)(H2O)(x) (x=0-6) Compounds

机译：矿物质启发晶体生长和物理性质Na2Cu（SO4）（2）和Na 2 M（SO 4）（2）（2）（H2O）（X）（X = 0-6）化合物的复述

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Single crystals and polycrystalline samples of a synthetic analogue of saranchinaite, Na2Cu(SO4)(2), have been prepared by two different methods. The structural analysis revealed unusual heptahedral CuO7 coordination [4 + 1 + 2] of Cu2+ cations in its crystal structure. The title compound crystallizes in the noncentrosymmetric space group P2(1) and exhibits the averaged nonlinear coefficient d = 1.4[d(14)(SiO2)] approximate to 0.5 pm/V. Electrochemical tests showed a limited electrochemical performance and low mobility of Na ions in the structure. The magnetic properties of Na2Cu(SO4)(2) reflect its crystal structure with half of copper cations as mainly paramagnetic and the other half as strongly engaged in antiferromagnetic dimer interactions. Analysis of the synthesis methods for preparation of the other Na-containing anhydrous sulfates is reported. Dehydration of the Na2M(SO4)(2)(H2O)(x) (x = 0-6) phases, various structure types, and the structural complexity of Na2M(SO4)(2) (M = Mn, Co, Ni, Cu, Zn, Cd) compounds are also discussed.

机译：通过两种不同的方法制备了Saranchinite，Na 2Cu（SO 4）（2）的合成类似物的单晶和多晶样品。结构分析显示了其晶体结构中的不寻常的七萜类CuO7配位[4 + 1 + 2] Cu2 +阳离子。标题化合物在非浓对称空间组P2（1）中结晶，并显示平均非线性系数＆ D＆ = 1.4 [D（14）（SiO2）]近似为0.5 pm / v。电化学测试显示了结构中的电化学性能和Na离子的低迁移率。 Na2Cu（SO4）（2）的磁性性能反映其晶体结构，其中一半的铜阳离子为主要是顺磁性，另一半在强烈地接合反铁磁性二聚体相互作用。据报道了对制备其他含Na无水硫酸盐的合成方法的分析。 Na 2M（SO 4）（2）（H 2 O）（X）（X = 0-6）相的脱水，各种结构类型和Na 2M（SO 4）（2）（M = Mn，Co，Ni，还讨论了Cu，Zn，Cd）化合物。

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《Crystal growth & design》 |2019年第2期|共12页
作者
Kovrugin Vadim M.; Nekrasova Diana O.; Siidra Oleg I.; Mentre Olivier; Masquelier Christian; Stefanovich Sergey Yu.; Colmont Marie;
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St Petersburg Univ Dept Crystallog St Petersburg 199034 Russia;

St Petersburg Univ Dept Crystallog St Petersburg 199034 Russia;

St Petersburg Univ Dept Crystallog St Petersburg 199034 Russia;

Univ Lille 1 UMR 8181 UCCS F-59655 Villeneuve Dascq France;

Univ Picardie Jules Verne UMR 7314 LRCS F-80039 Amiens France;

Moscow MV Lomonosov State Univ Dept Chem Leninskie Gory 1 Moscow 119991 Russia;

Univ Lille 1 UMR 8181 UCCS F-59655 Villeneuve Dascq France;

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中图分类晶体学;
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1. Mineral-Inspired Crystal Growth and Physical Properties Na2Cu(SO4)(2) and Review of Na2M(SO4)(2)(H2O)(x) (x=0-6) Compounds [J] . Kovrugin Vadim M., Nekrasova Diana O., Siidra Oleg I., Nature reviews Cancer . 2019,第2期

机译：矿物机制晶体生长和物理性质Na 2Cu（SO4）（2）和Na 2 M（SO 4）（2）（2）（H2O）（X）（X = 0-6）化合物的审查
2. Synthesis, crystal structure and magnetic properties of the cobalt(II) chain [Co(bipym)(H2O)(2)](NO3)(2) and the dinuclear compounds [Co-2(bipym)(3)(H2O)(4)](NO3)(4)center dot 2H(2)O and [Co-2(bipym)(3)(H2O)(2)(SO4)(2)]center dot 12H(2)O [J] . De Munno G., Julve M., Lloret F., New Journal of Chemistry . 1998,第3期

机译：钴（II）链[Co（bipym）（H2O）（2）]（NO3）（2）和双核化合物[Co-2（bipym）（3）（H2O）（ 4）]（NO3）（4）中心点2H（2）O和[Co-2（bipym）（3）（H2O）（2）（SO4）（2）]中心点12H（2）O
3. Growth, structure and properties of (K-1 (-) (x)(NH4)(x))(9)H-7(SO4)(8)center dot H2O crystals [J] . Dmitricheva E. V., Makarova I. P., Grebenev V. V., Solid state ionics . 2014,第Pta1期

机译：（K-1（-）（x）（NH4）（x））（9）H-7（SO4）（8）中心点H2O晶体的生长，结构和性质
4. Preparation and characterization of composite material Na2SO4·10H2O - KA1(SO4)2·12H2O for thermal storage [C] . M Zheng, J W Luo, Y H Zhang International Conference on New Material and Chemical Industry . 2017

机译：复合材料Na2SO4·10H2O-Ka1（SO4）2·12H2O用于热储存的制备及表征
5. New phases in the hydrous ferric sulfate system, a supporting argument that the mineral lausenite is of formula Fe2(SO4 )3·5H2O and the crystal structure refinement and hydrogen bonding scheme of the minerals quenstedtite and romerite [D] . Westland, Robin Elizabeth 2012

机译：含水硫酸铁体系中的新相，支持的论据是，矿物绿铁矿的分子式为Fe2（SO4）3·5H2O，以及芒硝和硅镁矿矿物的晶体结构细化和氢键合方案
6. Compounding MgCl2·6H2O with NH4Al(SO4)2·12H2O or KAl(SO4)2·12H2O to Obtain Binary Hydrated Salts as High-Performance Phase Change Materials [O] . Wanchun Sun, Yan Zhou, Jinxin Feng, 2019

机译：将MgCl2·6H2O与NH4Al（SO4）2·12H2O或KAl（SO4）2·12H2O混合以获得二元水合盐作为高性能相变材料
7. Investigation into the dehydration of selenate doped Na2M(SO4)2·2H2O (M = Mn, Fe, Co and Ni): Stabilisation of the high Na content alluaudite phases Na3M1.5(SO4)3-1.5x(SeO4)1.5x (M = Mn, Co and Ni) through selenate incorporation [O] . L.L. Driscoll, E. Kendrick, K.S. Knight, 2018

机译：研究硒酸酯掺杂Na2M（SO4）2·2H2O（M = Mn，Fe，Co和Ni）的脱水：高Na含量血统相对于Na3M1.5（SO 4）3-1.5x（SEO4）1.5x（SEO4）1.5x（ M = Mn，Co和Ni）通过硒化物融合

Mineral-Inspired Crystal Growth and Physical Properties Na2Cu(SO4)(2) and Review of Na2M(SO4)(2)(H2O)(x) (x=0-6) Compounds

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