A New Porous Three-Dimensional Iron(II) Coordination Polymer with Solvent-Induced Reversible Spin-Crossover Behavior

Meng Yan; Dong Yan-Jie; Yan Zheng; Chen Yan-Cong; Song Xiao-Wei; Li Quan-Wen; Zhang Chuan-Lei; Ni Zhao-Ping; Tong Ming-Liang

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A New Porous Three-Dimensional Iron(II) Coordination Polymer with Solvent-Induced Reversible Spin-Crossover Behavior

机译：具有溶剂诱导的可逆旋转交叉行为的新多孔三维铁（II）配位聚合物

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A new Hofmann-type porous coordination polymer [Fe(dpni){Ag-(CN)(2)}(2)]center dot 4CH(3)CN (dpni = N,N'-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide) with the topology of pcu net has been synthesized. It exhibits two-step spin-crossover behavior. Moreover, reversible changes between incomplete and two-step spin-crossover properties were associated with the desorption/resorption of the CH3CN solvent molecules.

机译：新的Hofmann型多孔配位聚合物[Fe（DPNI）{Ag-（CN）（2）}（2）]中心点4CH（3）CN（DPNI = N，N'-二 - （4-吡啶基） - 1,4,5,8-萘甲苯甲基甲基甲基甲基甲基甲基甲基甲基甲基甲基甲基甲基甲基甲醛。它表现出两步的旋转交叉行为。此外，不完全和两步自旋交叉特性之间的可逆变化与CH 3CN溶剂分子的解吸/再吸收有关。

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来源
《Crystal growth & design》 |2018年第9期|共6页
作者
Meng Yan; Dong Yan-Jie; Yan Zheng; Chen Yan-Cong; Song Xiao-Wei; Li Quan-Wen; Zhang Chuan-Lei; Ni Zhao-Ping; Tong Ming-Liang;
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作者单位

Anqing Normal Univ Anhui Higher Educ Inst Key Lab Funct Coordinat Cpds Anhui Prov Key Lab Optoelect &

Magnetism Funct Ma Anqing 246011 Peoples R China;

Anqing Normal Univ Anhui Higher Educ Inst Key Lab Funct Coordinat Cpds Anhui Prov Key Lab Optoelect &

Magnetism Funct Ma Anqing 246011 Peoples R China;

Jiaxing Univ Coll Biol Chem Sci &

Engn Jiaxing 314001 Peoples R China;

Sun Yat Sen Univ Sch Chem Minist Educ Key Lab Bioinorgan &

Synthet Chem Guangzhou 510275 Guangdong Peoples R China;

Anqing Normal Univ Anhui Higher Educ Inst Key Lab Funct Coordinat Cpds Anhui Prov Key Lab Optoelect &

Magnetism Funct Ma Anqing 246011 Peoples R China;

Sun Yat Sen Univ Sch Chem Minist Educ Key Lab Bioinorgan &

Synthet Chem Guangzhou 510275 Guangdong Peoples R China;

Anqing Normal Univ Anhui Higher Educ Inst Key Lab Funct Coordinat Cpds Anhui Prov Key Lab Optoelect &

Magnetism Funct Ma Anqing 246011 Peoples R China;

Sun Yat Sen Univ Sch Chem Minist Educ Key Lab Bioinorgan &

Synthet Chem Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Sch Chem Minist Educ Key Lab Bioinorgan &

Synthet Chem Guangzhou 510275 Guangdong Peoples R China;

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正文语种 eng
中图分类晶体学;
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1. 新型1,4-萘二甲酸铁多孔配位聚合物的合成和晶体结构及其吸附性质 [J] . 陈金喜, 孟伟伟, 张若冰东南大学学报（英文版） . 2011,第001期
2. A New Porous Three-Dimensional Iron(II) Coordination Polymer with Solvent-Induced Reversible Spin-Crossover Behavior [J] . Meng Yan, Dong Yan-Jie, Yan Zheng, Crystal growth & design . 2018,第9期

机译：具有溶剂诱导的可逆旋转交叉行为的新多孔三维铁（II）配位聚合物
3. Porous coordination polymers based on azamacrocyclic complex: syntheses, solvent-induced reversible crystal-to-crystal transformation and gas sorption properties [J] . Xiang Jiang, Zijian Li, Yanyun Zhai CrystEngComm . 2014,第5期

机译：基于氮杂大环配合物的多孔配位聚合物：合成，溶剂诱导的可逆晶体间转化和气体吸附性能
4. Co-ligand and Solvent Effects on the Spin-Crossover Behaviors of PtS-type Porous Coordination Polymers [J] . Xiang-Yi Chen, Rong-Bin Huang, Lan-Sun Zheng, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第10期

机译：配体和溶剂对PtS型多孔配位聚合物自旋交叉行为的影响
5. Spin-crossover and Unusual Magnetization Behavior in Novel Cobalt and Iron Coordination Polymers of Pyridazine [C] . Tao Yi, Susumu Kitagawa, Katsunori Mochizuki, China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena . 2000

机译：吡啶啶新钴和铁配位聚合物中的旋转交叉和异常磁化行为
6. Syntheses and solid-state structures of tris(pyrazolyl)methane complexes of iron(II) with unique spin-crossover behaviors and group 1 and 2 metals. [D] . Little, Christine Ann. 2001

机译：铁（II）的三（吡唑基）甲烷配合物的合成和固态结构，具有独特的自旋交叉行为以及第1和第2组金属。
7. Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron(ii) incorporating tetrathiafulvalene [O] . Ya-Ru Qiu, Long Cui, Pei-Yu Cai, 2020

机译：增强介电性耦合到包含四硫甲戊烯的一维聚合物铁（II）中的旋转交叉
8. Porous coordination polymers based on azamacrocyclic complex: syntheses, solvent-induced reversible crystal-to-crystal transformation and gas sorption properties [O] . Jiang Xiang, Li Zijian, Zhai Yanyun, 2014

机译：基于氮杂大环配合物的多孔配位聚合物：合成，溶剂诱导的可逆晶体-晶体转化和气体吸附性能

A New Porous Three-Dimensional Iron(II) Coordination Polymer with Solvent-Induced Reversible Spin-Crossover Behavior

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