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Research on the surface morphological and electrochemical modification of polyvinyl chloride induced by KrF and ArF excimer laser direct writing

机译:KRF和ARF准分子激光直接写作诱导聚氯乙烯的表面形态学和电化学改性研究

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To obtain superior performance in adhesion, polyvinyl chloride (PVC) substrates were modified by excimer laser direct writing with different operating wavelengths, scanning speeds, and laser fluences. The induced morphological and electrochemical changes were detailedly tested and analyzed. Microchannels were formed on the surfaces of the PVC substrates due to the laser ablation, where the melted-resolidified droplet-like structures were distributed uniformly and can significantly improve the mechanical interlock. Furthermore, according to the Fourier transform infrared spectroscopy and x-ray photoelectron spectroscopy analyses, Lewis bases such as hydroxyl and carbonyl were formed after laser treatment, which is beneficial to the adhesion strength. These mechanical and chemical modifications may play positive roles in enhancing the bonding strength of the PVC edge bandings. (C) 2020 Optical Society of America
机译:为了获得良好的粘合性能,通过不同的操作波长,扫描速度和激光流量通过准分子激光直接写入来改变聚氯乙烯(PVC)底物。 细节测试和分析了诱导的形态和电化学改变。 由于激光烧蚀,在PVC基板的表面上形成微通道,其中熔化的固化的液滴状结构均匀分布并且可以显着改善机械互锁。 此外,根据傅里叶变换红外光谱和X射线光电子能谱分析,在激光处理后形成诸如羟基和羰基的Lewis碱,这对粘合强度有益。 这些机械和化学修饰可能起到增强PVC边缘侧边缘的粘合强度的阳性作用。 (c)2020美国光学学会

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    《Applied optics》 |2020年第13期|共10页
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