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Photo-induced luminescence degradation in Ce, Yb co-doped yttrium aluminum garnet phosphors

机译:Ce,Yb共掺杂Yttrium铝石榴石磷光体的光诱导的发光劣化

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摘要

Photon-induced luminescence degradation of Ce, Yb co-doped yttrium aluminum garnet phosphors with different Yb concentrations under 457 nm irradiation is studied for the first time, to the best of our knowledge. The degradation behavior is more significant in nano-phosphors prepared via the solgel method, compared with bulkier samples prepared via solid-state reaction. Photoluminescence intensity of Ce3+ ions experiences a drop after initial illumination, due to photoionization of Ce3+ ions, whereas the down-converted luminescence of Yb3+ ions remains relatively stable. Co-doping Yb3+ contributes to the luminescence drop of Ce3+ with the excessive Yb3+ ions serving as additional electron traps. The results are in support of a charge transfer process. (C) 2018 Optical Society of America.
机译:CE的光子诱导的发光劣化,YB具有不同YB浓度的YB共掺杂的钇铝石榴石磷光体,首次研究了我们的知识。 与通过固态反应制备的抗底焊样品相比,降解行为在通过溶胶方法制备的纳米磷光体中更显着。 CE3 +离子的光致发光强度在初始照明之后经历掉落,而CE3 +离子的光相,而YB3 +离子的下转化发光仍然相对稳定。 共掺杂YB3 +有助于CE3 +的发光下降,其用作额外的电子捕集器的过量的YB3 +离子。 结果支持电荷转移过程。 (c)2018年光学学会。

著录项

  • 来源
    《Applied optics》 |2018年第26期|共7页
  • 作者

    Tang Liang; Ye Huiqi; Xiao Dong;

  • 作者单位

    Chinese Acad Sci Natl Astron Observ Nanjing Inst Astron Opt &

    Technol Nanjing 210042 Jiangsu Peoples R China;

    Chinese Acad Sci Natl Astron Observ Nanjing Inst Astron Opt &

    Technol Nanjing 210042 Jiangsu Peoples R China;

    Chinese Acad Sci Natl Astron Observ Nanjing Inst Astron Opt &

    Technol Nanjing 210042 Jiangsu Peoples R China;

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  • 正文语种 eng
  • 中图分类 应用;
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