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The effect of3Dstructure design on fire behavior of polyethylene terephthalate glycol containing aluminum hypophosphite and melamine cyanurate

机译:3D结构设计对含铝磷酸铝和三聚氰胺氰基乙二醇的聚对苯二甲酸乙二醇酯的火灾行为的影响

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摘要

Effect of the shape of 3D printed samples on fire behavior of polyethylene terephthalate glycol (PET-G) and PET-G additivated with a mix of aluminum hypophosphite (AHP) and melamine cyanurate as flame retardant, was investigated. The additives improved fire performance (e.g., maximum average rate of heat emission, total oxygen consumption, heat release rate indices) irrespective of structural complexity, favoring carbonaceous char formation. However, at increasing structural complexity, they promoted higher release of smoke, compared to neat PET-G, because of a change in the prevalent retardation mechanism, which became dominated by the flame inhibition action of AHP. Consequently, the synergistic effect obtained combining the two additives, was hindered. Impact of product design on mechanisms of fire retardation helps in devising engineering solutions aimed at meeting required level of fire-safety performance, which should be tailored to the specific product.
机译:研究了3D打印样品的形状对聚对苯二甲酸乙二醇酯(PET-G)和添加次磷酸铝(AHP)和三聚氰胺氰尿酸盐作为阻燃剂的PET-G的着火行为的影响。添加剂改善了燃烧性能(例如,最大平均放热率、总耗氧量、热释放率指数),而与结构复杂性无关,有利于碳质炭的形成。然而,随着结构复杂性的增加,与纯PET-G相比,它们促进了更高的烟雾释放,因为普遍的阻燃机制发生了变化,而AHP的阻燃作用成为主导。因此,这两种添加剂的协同效应受到阻碍。产品设计对阻燃机制的影响有助于设计工程解决方案,以满足消防安全性能的要求,并应针对特定产品进行定制。

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