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Urushiol titanium polymer-based composites coatings for anti-corrosion and antifouling in marine spray splash zones

机译:尿道钛聚合物基复合材料涂层用于船舶喷雾溅区的防腐蚀和防污

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摘要

Seawater is highly corrosive, and the alternating dry and wet environment can cause severe corrosion in metal equipment. Moreover, marine equipment is also seriously affected by marine biofouling. These harsh conditions pose a serious threat to the integrity of marine equipment as well as their associated maritime activities and necessitate the development of effective coatings to minimize damage to the equipment. Urushiol titanium polymer/acrylic resin (UTP/AR) composite materials were developed. Then, marine anti-corrosion and antifouling coatings were prepared from the UTP/AR composite materials using rosin-modified Cu2O as an antifoulant. The composite coating with a UTP:AR mass ratio of 1:1 (UTP/AR3) showed the best chemical resistance and light aging resistance. UTP/AR3 also exhibited a good corrosion current density (2.009 x 10(-7) A cm(-2)) and corrosion potential (-0.5007 V), further indicating that the UTP/AR composite coatings have excellent anti-corrosive properties. Marine field tests showed that the UTP/AR/Cu2O composite coatings with rosin-modified Cu2O contents less than 20% showed stable, long-term antifouling performance after immersion in seawater for 360 day. Briefly, the UTP/AR/Cu2O composite coatings have broad application prospects in the marine industry for materials in the spray splash zone.
机译:海水具有很强的腐蚀性,干湿交替的环境会对金属设备造成严重腐蚀。此外,海洋设备也受到海洋生物污染的严重影响。这些恶劣条件对海洋设备及其相关海上活动的完整性构成严重威胁,需要开发有效的涂层,以尽量减少对设备的损坏。研制了漆酚钛聚合物/丙烯酸树脂(UTP/AR)复合材料。然后,以松香改性Cu2O为防污剂,用UTP/AR复合材料制备了海洋防腐防污涂料。UTP:AR质量比为1:1(UTP/AR3)的复合涂层具有最佳的耐化学性和耐光老化性。UTP/AR3还表现出良好的腐蚀电流密度(2.009 x 10(-7)a cm(-2))和腐蚀电位(-0.5007 V),进一步表明UTP/AR复合涂层具有优异的防腐性能。海上现场试验表明,松香改性Cu2O含量小于20%的UTP/AR/Cu2O复合涂层在海水中浸泡360天后,表现出稳定、长期的防污性能。简单地说,UTP/AR/Cu2O复合涂层在船舶工业中具有广阔的应用前景。

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