New water-soluble copolymers of 2-methacryloyloxyethyl phosphorylcholine for surface modification

Nazarova Olga; Chernova Eugenia; Dobrodumov Anatoliy; Zolotova Yulia; Bezrukova Marina; Nekrasova Tatyana; Vlasova Elena; Panarin Eugeniy

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New water-soluble copolymers of 2-methacryloyloxyethyl phosphorylcholine for surface modification

机译：用于2-甲基丙烯酰氧基乙基磷酸胆碱的新水溶性共聚物，用于表面改性

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摘要

New copolymers of 2-methacryloyloxyethyl phosphorylcholine with 2-Deoxy-2-methacrylamido-D-glucose, N-vinylpyrrolidone, and N-vinyl-N-methylacetamide were synthesized and characterized; the obtained copolymers contained 10-50 mol% of phosphorylcholine moieties, and their molecular masses ranged from 1.05 x 10(5) to 4.40 x 10(5). Reactivity ratios of the monomers were estimated. Conformational states of the copolymers in aqueous solutions were studied. The synthesized copolymer was grafted onto the surface of carbon fiber biosorbent using gamma-radiation.

机译：合成并表征了2-甲基丙烯酰氧乙基磷酰胆碱与2-脱氧-2-甲基丙烯酰胺基-D-葡萄糖、N-乙烯基吡咯烷酮和N-乙烯基-N-甲基乙酰胺的新共聚物；所得共聚物含有10-50mol%的磷酰胆碱部分，其分子量范围为1.05x10（5）至4.40x10（5）。估计了单体的反应率。研究了共聚物在水溶液中的构象状态。利用γ射线将合成的共聚物接枝到碳纤维生物吸附剂表面。

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来源
《Journal of Applied Polymer Science》 |2021年第18期|共11页
作者
Nazarova Olga; Chernova Eugenia; Dobrodumov Anatoliy; Zolotova Yulia; Bezrukova Marina; Nekrasova Tatyana; Vlasova Elena; Panarin Eugeniy;
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作者单位

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

Russian Acad Sci Inst Macromol Cpds Bolshoy Pr VO 31 St Petersburg 199004 Russia;

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正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
biomedical applications; coatings; copolymers; hydrophilic polymers;

机译：生物医学应用;涂料;共聚物;亲水聚合物;

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2. Study on Surface Modification of Glass Bead by a Block Copolymer Coupling Agent [J] . LI Yin, ZHANG Bing, ZHOU Xiao-dong 东华大学学报（英文版） . 2008,第004期
3. Water-soluble and amphiphilic phospholipid copolymers having 2-methacryloyloxyethyl phosphorylcholine units for the solubilization of bioactive compounds [J] . Ishihara Kazuhiko, Mu Mingwei, Konno Tomohiro Journal of biomaterials science . 2018,第7a9期

机译：具有2-甲基丙烯酰氧基乙基磷酸胆碱单元的水溶性和两亲磷脂共聚物，用于溶解生物活性化合物
4. Photoinduced atom transfer radical polymerization in a polar solvent to synthesize a water-soluble poly(2-methacryloyloxyethyl phosphorylcholine) and its block-type copolymers [J] . Chantasirichot Surasak, Inoue Yuuki, Ishihara Kazuhiko Polymer: The International Journal for the Science and Technology of Polymers . 2015,第Null期

机译：极性溶剂中的光诱导原子转移自由基聚合反应，以合成水溶性聚（2-甲基丙烯酰氧基乙基磷酰胆碱）及其嵌段共聚物
5. Modification of a polyethersulfone membrane with a block copolymer brush of poly(2-methacryloyloxyethyl phosphorylcholine-co-glycidyl methacrylate) and a branched polypeptide chain of Arg–Glu–Asp–Val [J] . Xiaoqin Niu, Dan Li, Yuhong Chen, RSC Advances . 2019,第44期

机译：用聚（2-甲基丙烯酰氧基乙基磷酰胆碱-甲基丙烯酸缩水甘油酯-co-缩水甘油酯）嵌段共聚物刷和Arg-Glu-Asp-Val的支链多肽链修饰聚醚砜膜
6. Surface Modification by Grafting with Biocompatible 2-Methacryloyloxyethyl Phosphorylcholine for Microfluidic Devices [C] . James Sibarani, Tomohiro Konno, Madoka Takai, Asian Symposium on biomedical materials . 2007

机译：用生物相容性2-甲基丙烯酰氧基乙基磷酸胆碱用于微流体装置的表面改性
7. Surface Modification of Polydimethyl Siloxane Using Polyethylene Oxide Copolymers. [D] . Manchanda, Shikha. 2012

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8. Cyclic olefin copolymer based microfluidic devices for biochip applications: Ultraviolet surface grafting using 2-methacryloyloxyethyl phosphorylcholine [O] . Rajeeb K. Jena, C. Y. Yue 2012

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10. Water-Soluble and Optically pH-Sensitive Single-Walled Carbon Nanotubes from Surface Modification [R] . Zhao, W. , Song, C. , Pehrsson, P. E. 2002

机译：表面改性的水溶性和光学pH敏感单壁碳纳米管

New water-soluble copolymers of 2-methacryloyloxyethyl phosphorylcholine for surface modification

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