首页> 外文期刊>Journal of Applied Polymer Science >Layer-by-layerassembled bagasse to enhance the fire safety of epoxy resin: A renewable environmental friendly flame retardant
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Layer-by-layerassembled bagasse to enhance the fire safety of epoxy resin: A renewable environmental friendly flame retardant

机译:逐层配备甘蔗渣,增强环氧树脂的火灾安全性:可再生环境友好的阻燃剂

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摘要

In an effort to make rational use of resources, wasted bagasse were collected, and then fabricated by layer-by-layer (LbL) assembly to prepare an environmentally benign flame retardant for epoxy resin (EP). Six chitosan/ammonum polyphosphate bilayers were successfully deposited on the surface of bagasse, which endows EP/6BL@BF composites with a limiting oxygen index value of 24.1% and V-1 rating in UL-94 test. Compared with untreated bagasse, cone calorimetry test reveals that the incorporation of6BL@BF reduces the peak heat release rate and total heat release by 64.6% and 13.2%, respectively. Besides, expandable graphite (EG) was combined with6BL@BF to further enhance the fire safety and thermal stability of EP composites. Furthermore, the gas and condensed phase analysis of EP/6BL@BF/EG-3 composite was investigated by TG-IR, scanning electronic microscopy, Laser Raman spectroscopy, and X-ray photoelectron spectroscopy, and the flame retardant mechanism of6BL@BF/EG was proposed. Finally, the mechanical properties of EP composites were investigated systematically.
机译:为了合理利用资源,将废弃的甘蔗渣收集起来,通过层层(LbL)组装,制备了一种环保型环氧树脂阻燃剂(EP)。在甘蔗渣表面成功地沉积了六层壳聚糖/聚磷酸铵双层膜,赋予了EP/6BL@BF极限氧指数为24.1%,UL-94试验中V-1等级的复合材料。与未经处理的甘蔗渣相比,锥形量热试验表明of6BL@BF峰值放热率和总放热率分别降低64.6%和13.2%。此外,还结合了可膨胀石墨(EG)with6BL@BF进一步提高EP复合材料的防火安全性和热稳定性。此外,对EP进行了气相和凝聚相分析/6BL@BF/通过TG-IR、扫描电镜、激光拉曼光谱和X射线光电子能谱对EG-3复合材料进行了研究,并对其阻燃机理进行了探讨of6BL@BF/有人提议。最后,系统地研究了EP复合材料的力学性能。

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