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Photo-curing3Dprinting robust elastomers with ultralow viscosity resin

机译:光固化3dprinting强大的弹性体,具有超低粘度树脂

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摘要

Photosensitive resins with ultralow viscosity suitable for the silicone-based elastomers by 3D printing were reported. Based on the facile one-pot strategy which involved photo-polymerization of hydroxyethyl acrylate (HEA) and sol-gel transition process of methyltrimethoxysilane (MTMS), silicone-based elastomers with tunable mechanical properties could be obtained by adjusting the ratio of HEA and MTMS as needed. Due to the physically cross-linked network formed by hydrogen bonds between hydroxyl group of polyhydroxypropyl acrylate (PHEA) and the chemically cross-linked network formed by MTMS, the stress and strain of printed elastomers reached 3.75 MPa and 205% respectively demonstrating its performance has reached the average level of already reported photo-curable elastomers. The photosensitive resins with high curing rate and low viscosity are suitable for 3D printing technique.
机译:报道了一种适用于三维打印硅基弹性体的超低粘度光敏树脂。基于丙烯酸羟乙酯(HEA)的光聚合和甲基三甲氧基硅烷(MTMS)的溶胶-凝胶转变过程的简便一锅法,可根据需要调节HEA和MTMS的比例,获得机械性能可调的硅基弹性体。由于聚羟丙基丙烯酸酯(PHEA)的羟基与MTMS形成的化学交联网络之间通过氢键形成物理交联网络,印刷弹性体的应力和应变分别达到3.75 MPa和205%,表明其性能已达到已报道的光固化弹性体的平均水平。高固化率、低粘度的光敏树脂适用于3D打印技术。

著录项

  • 来源
    《Journal of Applied Polymer Science》 |2021年第10期|共12页
  • 作者单位

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Engn Beijing 100029 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 高分子化合物工业(高聚物工业);
  • 关键词

    3D printing; elastomer; photosensitive resin; ultralow viscosity;

    机译:3D打印;弹性体;光敏树脂;超级粘度;

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