Fabrication and characterization of poly(1,4-cyclohexanedimthylene terephthalate-co-1,4-cyclohxylenedimethylene 2,6-naphthalenedicarboxylate) (PCTN) copolyester film: A novel copolyester film with exceptional performances for next generation flexible electronic devices

Hussain Fiaz; Park Sangwon; Jeong Jaemin; Jeong Euichul; Kang Soo-Jung; Yoon Kyunghwan; Kim Jinhwan

首页> 外文期刊>Journal of Applied Polymer Science >Fabrication and characterization of poly(1,4-cyclohexanedimthylene terephthalate-co-1,4-cyclohxylenedimethylene 2,6-naphthalenedicarboxylate) (PCTN) copolyester film: A novel copolyester film with exceptional performances for next generation flexible electronic devices

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Fabrication and characterization of poly(1,4-cyclohexanedimthylene terephthalate-co-1,4-cyclohxylenedimethylene 2,6-naphthalenedicarboxylate) (PCTN) copolyester film: A novel copolyester film with exceptional performances for next generation flexible electronic devices

机译：聚（1,4-环己二酮对苯二甲酸乙二醇酯-CO-1,4-环己二甲基2,6-萘二甲硅烷酯）（PCTN）共聚酯薄膜的制备和表征）：一种新型共聚酯薄膜，具有卓越的下一代柔性电子器件的性能

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A novel, semi-crystalline poly(1,4-cyclohexylenedimethylene terephthalate-co-1,4-cyclohexylene dimethylene 2,6-naphthalenedicarboxylate) (PCTN) copolyester was synthesized and successfully extruded using an extruder attached with T-die. The extruded sheet was uniaxially cold-drawn into film at 150 degrees C, a temperature between glass transition temperature and melting temperature. The mechanical, thermal, thermo-mechanical, water barrier, and optical properties of developed film were characterized. Orientation of different phases was analyzed by X-ray diffraction. The actual chemical composition of PCTN copolyester was analyzed by nuclear magnetic resonance spectroscopy. Our results clearly indicated the thermal, dimensional stability, mechanical, and water barrier properties of PCTN films increased in a linear trend with draw ratio. It was also found that PCTN film has better water barrier property compared to conventional poly(ethylene terephthalate) (PET) and poly(ethylene 2,6-naphthalate) (PEN) films. Based on the exceptional performance properties, novel PCTN film may find a strong position as a substrate for next generation flexible electronics among various performance materials.

机译：合成了一种新型的半结晶聚（1,4-环己烯二甲基对苯二甲酸酯-co-1,4-环己烯二甲基-2,6-萘二甲酸酯）（PCTN）共聚酯，并使用带有T型模具的挤出机成功挤出。挤压板材在150摄氏度（介于玻璃化转变温度和熔化温度之间）下单轴冷拉成膜。对所制备薄膜的力学、热学、热机械、阻水性和光学性能进行了表征。通过X射线衍射分析了不同相的取向。用核磁共振波谱分析了PCTN共聚酯的实际化学组成。我们的结果清楚地表明，PCTN薄膜的热稳定性、尺寸稳定性、机械性能和防水性能随拉伸比呈线性增加。与传统的聚对苯二甲酸乙二醇酯（PET）和聚2,6-萘二甲酸乙二醇酯（PEN）薄膜相比，PCTN薄膜具有更好的防水性能。基于其优异的性能，新型PCTN薄膜有望在各种性能材料中成为下一代柔性电子器件的衬底。

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来源
《Journal of Applied Polymer Science》 |2021年第8期|共10页
作者
Hussain Fiaz; Park Sangwon; Jeong Jaemin; Jeong Euichul; Kang Soo-Jung; Yoon Kyunghwan; Kim Jinhwan;
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作者单位

Sungkyunkwan Univ Dept Polymer Sci &

Engn 2066 Seobu Ro Suwon 16419 Gyeonggi Do South Korea;

Sungkyunkwan Univ Dept Polymer Sci &

Engn 2066 Seobu Ro Suwon 16419 Gyeonggi Do South Korea;

Sungkyunkwan Univ Dept Polymer Sci &

Engn 2066 Seobu Ro Suwon 16419 Gyeonggi Do South Korea;

Dankook Univ Dept Mech Engn Yongin Gyeonggi Do South Korea;

Sungkyunkwan Univ Dept Polymer Sci &

Engn 2066 Seobu Ro Suwon 16419 Gyeonggi Do South Korea;

Dankook Univ Dept Mech Engn Yongin Gyeonggi Do South Korea;

Sungkyunkwan Univ Dept Polymer Sci &

Engn 2066 Seobu Ro Suwon 16419 Gyeonggi Do South Korea;

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正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
films; mechanical properties; optical properties; rheology; extrusion;

机译：电影;机械性能;光学性质;流变学;挤压;

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Fabrication and characterization of poly(1,4-cyclohexanedimthylene terephthalate-co-1,4-cyclohxylenedimethylene 2,6-naphthalenedicarboxylate) (PCTN) copolyester film: A novel copolyester film with exceptional performances for next generation flexible electronic devices

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