Selective enrichment of Ln(3+) (Ln = Yb; Er) and Cr3+ into SrF2 and ZnAl2O4 nanocrystals precipitated in fluorosilicate glass-ceramics: A dual mode optical temperature sensing study

Wadhwa Abhishek; Awasthi Pragati; Ren Kai; Xu Xiuxia; Qiao Xvsheng; Fan Xianping; Qian Guodong

首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >Selective enrichment of Ln(3+) (Ln = Yb; Er) and Cr3+ into SrF2 and ZnAl2O4 nanocrystals precipitated in fluorosilicate glass-ceramics: A dual mode optical temperature sensing study

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Selective enrichment of Ln(3+) (Ln = Yb; Er) and Cr3+ into SrF2 and ZnAl2O4 nanocrystals precipitated in fluorosilicate glass-ceramics: A dual mode optical temperature sensing study

机译：选择性富集LN（3+）（LN = Yb; ER）和Cr3 +进入SRF2和ZNAL2O4纳米晶体中的氟硅酸盐玻璃陶瓷：双模光学温度传感研究

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The dual mode optical thermometry offers precise temperature sensing with self-calibration merit. To realise this, an oxy-fluoride precursor glass was transformed to a semi-transparent glass-ceramic having simultaneously precipitated SrF2:Yb3+/Er3+ and ZnAl2O4:Cr3+ phases. Under 980 nm excitation, intense green up-conversion (UC) luminescence of Er3+: H-2(11/2), S-4(3/2) -> I-4(15/2) and under 535 nm excitation, enhanced red down-conversion (DC) luminescence lifetime of Cr3+: E-2, T-4(2) -> (4)A(2) was realized. Both the UC and DC transitions were highly reliant upon temperature. The fluorescence intensity ratio (FIR) study of erbium's thermally coupled energy states (H-2(11/2) and S-4(3/2)) produced maximum temperature sensing sensitivity values of 1.11% K-1 at 334 K and 0.66% K-1 at 275 K, respectively. Likewise, temperature dependent luminescence lifetime of Cr3+ attributed to the transitions arising from the parity forbidden (E-2 -> (4)A(2)) and spin allowed (T-4(2) -> (4)A(2)) relaxations produced maximum temperature sensing sensitivity value equal to 0.19% K-1 at 435 K.

机译：双模光学测温仪提供了具有自校准优点的精确温度传感。为了实现这一点，将含氧氟化物前体玻璃转变为同时沉淀SrF2:Yb3+/Er3+和ZnAl2O4:Cr3+相的半透明微晶玻璃。在980nm激发下，实现了Er3+：H-2（11/2）、S-4（3/2）->I-4（15/2）的强绿色上转换（UC）发光；在535nm激发下，实现了Cr3+：E-2、T-4（2）->（4）A（2）的增强红色下转换（DC）发光寿命。UC和DC转变都高度依赖于温度。对铒的热耦合能态（H-2（11/2）和s-4（3/2））的荧光强度比（FIR）研究分别在334 K和275 K时产生了1.11%K-1和0.66%K-1的最大感温灵敏度值。同样地，Cr3+的温度依赖性发光寿命归因于宇称禁止（E-2->（4）A（2））和自旋允许（T-4（2）->（4）A（2））弛豫引起的跃迁，在435 K下产生了等于0.19%K-1的最大感温灵敏度值。

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2021年第1期|共9页
作者
Wadhwa Abhishek; Awasthi Pragati; Ren Kai; Xu Xiuxia; Qiao Xvsheng; Fan Xianping; Qian Guodong;
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Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

Zhejiang Univ State Key Lab Silicon Mat Hangzhou 310027 Peoples R China;

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正文语种 eng
中图分类非晶态和类晶态;
关键词
Dual-phase glass-ceramics; Optical temperature sensing; Luminescence; Rare earths; Transition metals; Upconversion;

机译：双相玻璃陶瓷;光学温度感应;发光;稀土;过渡金属;上传;

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1. Yb3+/Ln(3+)/Cr3+ (Ln = Er, Ho) doped transparent glass ceramics: crystallization, Ln(3+) sensitized Cr3+ upconversion emission and multi-modal temperature sensing [J] . Chen Daqin, Liu Shen, Xu Wei, Journal of Materials Chemistry, C. materials for optical and electronic devices . 2017,第45期

机译：YB3 + / LN（3 +）/ CR3 +（LN = ER，HO）掺杂透明玻璃陶瓷：结晶，LN（3+）敏化CR3 +上转换发射和多模态温度传感
2. Anisotropic exchange interactions in hetero-one-dimensional Ln(3+)-M3+ systems (Ln(3+) = Er, Yb; M3+ = Cr, Fe-LS): Magnetometry and dual mode X-band electron paramagnetic resonance spectroscopic studies [J] . Tangoulis V, Estrader M, Figuerola A, Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature . 2007,第1期

机译：异一维Ln（3 +）-M3 +系统（Ln（3+）= Er，Yb; M3 + = Cr，Fe-LS）中的各向异性交换相互作用：磁力计和双模X波段电子顺磁共振光谱研究
3. Mesoporous SrF2 and SrF2:Ln~(3+) (Ln = Ce, Tb, Yb, Er) Hierarchical Microspheres: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties [J] . Cuimiao Zhang, Zhiyao Hou, Ruitao Chai The journal of physical chemistry, C. Nanomaterials and interfaces . 2010,第15期

机译：介孔SrF2和SrF2：Ln〜（3+）（Ln = Ce，Tb，Yb，Er）分层微球：水热合成，生长机理和发光性质
4. Optical Temperature Sensing of Core-shell Structured NaYF_4:Yb~(3+), Er~(3+)@NaYF_4 Nanocrystals with Different Shell Thickness [C] . Dongdong Li, Qiyue Shao, Yan Dong, International Conference on Sensors, Measurement and Intelligent Materials . 2015

机译：光学温度传感核心壳结构Nayf_4：YB〜（3+），ER〜（3 +）@ Nayf_4纳米晶体，具有不同的外壳厚度
5. Upconversion luminescence and favorable temperature sensing performance of eulytite-type Sr3Y(PO4)3:Yb3+/Ln3+ phosphors (Ln=Ho Er Tm) [O] . Weigang Liu, Xuejiao Wang, Qi Zhu, 2019

机译：磷锌矿型Sr3Y（PO4）3：Yb3 + / Ln3 +荧光粉（Ln = HoErTm）的上转换发光和良好的温度感应性能
6. Dual mode temperature sensing through luminescence lifetimes of F- and O-coordinated Cr3+ sites in fluorosilicate glass-ceramics [O] . Wang, C., Wadhwa, A., Cui, S., 2017

机译：通过氟硅酸盐玻璃陶瓷中F和O配位的Cr3 +位的发光寿命进行双模温度感测

Selective enrichment of Ln(3+) (Ln = Yb; Er) and Cr3+ into SrF2 and ZnAl2O4 nanocrystals precipitated in fluorosilicate glass-ceramics: A dual mode optical temperature sensing study

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