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Mixed alkaline earth modifiers effect on thermal, optical and structural properties of SrO-BaO-SiO2-B2O3-ZrO2 glass sealants

机译:混合碱土改性剂对Sro-BaO-SiO2-B2O3-ZrO2玻璃密封剂的热,光学和结构性能的影响

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摘要

Composition of (40-x)SrO-(x)BaO-45SiO(2)-10B(2)O(3)-5ZrO(2) (x=0,10,20,30 and 40 mol%) are synthesized by melt quench technique. The as prepared samples are characterized using various experimental techniques to study their structural, optical (insulating) and thermal expansion coefficient (TEC) to check their suitability as glass sealants. Alkaline earth mixed modifier effect is observed on all the properties. However, it is more pronounced when SrO/BaO modifiers ratio is approached to 1 in the present glasses. All glasses exhibit optical band gap in moderate insulating range viz. 3.2-3.8eV. TEC of as prepared glasses is also in required range of SOFC sealants except glass having x=20 mol% (SB-20). Softening temperature of all the glasses is higher than 700 degrees C except this glass. Based on present study, glass having x=10 mol% (SB-10) could be suitable as a sealant for intermediate temperature (600-800 degrees C) solid oxide fuel cell.
机译:采用熔融淬火技术合成了(40-x)SrO-(x)BaO-45SiO(2)-10B(2)O(3)-5ZrO(2)(x=0,10,20,30和40mol%)的化合物。使用各种实验技术对制备的样品进行表征,以研究其结构、光学(绝缘)和热膨胀系数(TEC),以检查其作为玻璃密封剂的适用性。在所有性能上均观察到碱土混合改性剂效应。然而,在目前的玻璃中,当SrO/BaO改性剂比率接近1时,这一点更加明显。所有玻璃都在中等绝缘范围内表现出光学带隙,即。3.2-3.8eV。制备玻璃的TEC也在SOFC密封剂的要求范围内,但x=20 mol%(SB-20)的玻璃除外。除此之外,所有玻璃的软化温度都高于700摄氏度。根据目前的研究,x=10 mol%(SB-10)的玻璃适合用作中温(600-800℃)固体氧化物燃料电池的密封剂。

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