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首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >One-to-one correlation between the kinetics of the enthalpy changes and the number of defects assumed responsible for structural relaxation in metallic glasses
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One-to-one correlation between the kinetics of the enthalpy changes and the number of defects assumed responsible for structural relaxation in metallic glasses

机译:焓变化的动力学与缺陷数量之间的一对一相关性,假设在金属眼镜中的结构松弛负责

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摘要

Parallel measurements of the enthalpy and high-frequency shear modulus changes occurring upon structural relaxation of five bulk metallic glasses are performed. An analysis showed that there exists a one-to-one correlation between the change of the molar enthalpy and the alteration of the number of defects calculated within the framework of the Interstitialcy theory on the basis of shear modulus relaxation data. The defect formation enthalpy derived using this correlation agrees quite well with this quantity accepted in the Interstitialcy theory.
机译:对五种大块金属玻璃在结构松弛时发生的焓和高频剪切模量变化进行了平行测量。分析表明,在基于剪切模量松弛数据的填隙理论框架内计算的摩尔焓变化和缺陷数量变化之间存在一对一的相关性。用这种关联式导出的缺陷形成焓与间隙理论中接受的这个量非常吻合。

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