In Situ Surface Coating of Squaric Acid with Conductive Polyaniline for a High-Capacity and Sustainable Lithium Battery Anode

Ghosh Arnab; Mitra Sagar

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In Situ Surface Coating of Squaric Acid with Conductive Polyaniline for a High-Capacity and Sustainable Lithium Battery Anode

机译：原位表面涂层用导电聚苯胺进行高容量和可持续的锂电池阳极

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摘要

Squaric acid (SA) has been investigated as a readily available organic anode material in rechargeable lithium batteries. To overcome both conductivity and dissolution problems related to organic compounds, SA was conformally coated with conductive polyaniline through a facile in situ chemical polymerization route. Polyaniline-coated SA exhibits a stable high capacity of 394 mAhg(-1) after 100 cycles at 100 mAg(-1) in lithium batteries. At 1 Ag-1 current density, polyaniline-coated SA (PANI-SA) shows long cycle life over 1000 cycles with 96.9% retention of initial reversible capacity. The reversible Li+ storage property of SA is revealed through ex situ NMR characterization.

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来源
《ChemElectroChem》 |2018年第1期|共7页
作者
Ghosh Arnab; Mitra Sagar;
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作者单位

Indian Inst Technol Dept Energy Sci &

Engn Electrochem Energy Storage Lab Mumbai 400076 Maharashtra India;

Indian Inst Technol Dept Energy Sci &

Engn Electrochem Energy Storage Lab Mumbai 400076 Maharashtra India;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
squaric acid; polyaniline; organic anode material; lithium batteries; ex situ NMR;

机译：种族酸;聚苯胺;有机阳极材料;锂电池;ex situ nmr;

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In Situ Surface Coating of Squaric Acid with Conductive Polyaniline for a High-Capacity and Sustainable Lithium Battery Anode

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