Bidirectional Access to Radical Cation Diels-Alder Reactions by Electrocatalysis

Ozaki Atsushi; Yamaguchi Yusuke; Okada Yohei; Chiba Kazuhiro

首页> 外文期刊>ChemElectroChem >Bidirectional Access to Radical Cation Diels-Alder Reactions by Electrocatalysis

【24h】

Bidirectional Access to Radical Cation Diels-Alder Reactions by Electrocatalysis

机译：双向进入自由基阳离子Diels-Alder通过电催化反应

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Umpolung is a classic and central concept in synthesis that produces a reversal of the normal reactivity of the molecules under study. The most straightforward method for umpolung involves an electron transfer reaction. The present study describes bidirectional access to radical cation Diels-Alder reactions by electrocatalysis. The radical cation either of transanethole or 9-methylanthracene could trigger the reaction, which was confirmed unambiguously through the use of silica-gel-supported substrates.

机译：None

著录项

来源
《ChemElectroChem》 |2017年第8期|共4页
作者
Ozaki Atsushi; Yamaguchi Yusuke; Okada Yohei; Chiba Kazuhiro;
展开▼
作者单位

Tokyo Univ Agr &

Technol Dept Appl Biol Sci 3-5-8 Saiwai Cho Fuchu Tokyo 1838509 Japan;

Tokyo Univ Agr &

Technol Dept Appl Biol Sci 3-5-8 Saiwai Cho Fuchu Tokyo 1838509 Japan;

Tokyo Univ Agr &

Technol Dept Chem Engn 2-24-16 Naka Cho Koganei Tokyo 1848588 Japan;

Tokyo Univ Agr &

Technol Dept Appl Biol Sci 3-5-8 Saiwai Cho Fuchu Tokyo 1838509 Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
cyclic voltammetry; Diels-Alder reactions; electrocatalysis; silica gel-supported substrate; umpolung;

机译：循环伏安;Diels-Alder反应;电殖分解;硅胶负载基板;Umpolung;

相似文献

外文文献
中文文献
专利

1. Radical Cation Diels-Alder Reactions of Non-Conjugated Alkenes as Dienophiles by Electrocatalysis [J] . Atsushi Ozaki, Yusuke Yamaguchi, Yohei Okada, 中国化学（英文版） . 2019,第006期
2. Radical cation salts induced domino reaction of anilines with enol ethers: Synthesis of 1,2,3,4-tetrahydroquinoline derivatives [J] . Xiao Dong Jia, Yan Ren, Cong Dde Huo, 中国化学快报（英文版） . 2011,第006期
3. Study on the reaction of N-alkylphenothiazine radical cations with 2,4-dinitrophenylhydrazine [J] . 中国化学快报（英文版） . 1994,第009期
4. Bidirectional Access to Radical Cation Diels-Alder Reactions by Electrocatalysis [J] . Ozaki Atsushi, Yamaguchi Yusuke, Okada Yohei, ChemElectroChem . 2017,第8期

机译：双向获得电催化的激进阳离子Diels-Alder反应
5. Selective electrocatalysis of alkene oxidations in aqueous media. Electrochemical and spectral characterization of oxo-ferryl porphyrin, oxo-ferryl porphyrin radical cation and their reaction products with alkenes at room temperature [J] . Mao-huang Liu, Y. Oliver Su Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1998,第1期

机译：水性介质中烯烃氧化的选择性电催化。氧-轮渡卟啉，氧-轮卟啉自由基阳离子及其与烯烃的反应产物在室温下的电化学和光谱表征
6. Radical Cation Diels-Alder Reactions by TiO2 Photocatalysis [J] . Nakayama Kaii, Maeta Naoya, Horiguchi Genki, Organic letters . 2019,第7期

机译：通过TiO2光催化分解的激进阳离子Diels - Alder反应
7. Redox Tag-Assisted Radical Cation Diels-Alder Reactions [C] . Yohei Okada 日本化学会春季年会講演予稿集 . 2018

机译：氧化还原标签辅助自由基阳离子Diels反应
8. Development of two organocatalytic photoredox transformations: The enantioselective cation radical Diels-Alder reaction and the anti-Markovnikov hydroamination of alkenes. [D] . Nguyen, Tien M. 2014

机译：两种有机催化光氧化还原转化的发展：对映选择性阳离子自由基Diels-Alder反应和烯烃的反马尔可夫尼科夫氢化胺化反应。
9. Enantioselective counter-anions in photoredox catalysis: the asymmetric cation radical Diels-Alder reaction [O] . Peter D. Morse, Tien M. Nguyen, Cole L. Cruz, -1

机译：光氧化还原催化中的对映选择性反阴离子：不对称阳离子自由基Diels-Alder反应
10. The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene- Diene Format [O] . David B. Rusterholz, David B. Gorman, Paul G. Gassman 2013

机译：分子内自由基引发的Diene-Diene形式的Diels-Alder反应
11. Formation of substituted benzene radical cations via ion/molecule reactions with iodobenzene [R] . Glish, G. L., McLuckey, S. A. 1991

机译：通过与碘苯的离子/分子反应形成取代的苯自由基阳离子

Bidirectional Access to Radical Cation Diels-Alder Reactions by Electrocatalysis

摘要

著录项

相似文献

相关主题

期刊订阅