Spontaneous Deracemizations

Buhse Thomas; Cruz Jose-Manuel; Noble-Teran Maria E.; Hochberg David; Ribo Josep M.; Crusats Joaquim; Micheau Jean-Claude

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Spontaneous Deracemizations

机译：自发终止

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Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality research. In the absence of any chiral inductors, an achiral substance or a racemic composition is driven into an enantioenriched or even homochiral state through a selective energy input, e.g., chemical potential, photoirradiation, mechanical grinding, ultrasound waves, thermal gradients, etc. The most prominent examples of such transformations are the Soai reaction and the Viedma deracemization. In this review, we track the most recent developments in this topic and recall that many other deracemizations have been reported for solutions from mesophases to conglomerate crystallizations. A compiled set of simply available achiral organic, inorganic, organometallic, and MOF compounds, yielding conglomerate crystals, should give the impetus to realize new experiments on spontaneous deracemizations. Taking into account thermodynamic constraints, modeling efforts have shown that structural features alone are not sufficient to describe spontaneous deracemizations. As a guideline of this review, particular attention is paid to the physicochemical origin and symmetry requirements of such processes.

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《Chemical Reviews》 |2021年第4期|共83页
作者
Buhse Thomas; Cruz Jose-Manuel; Noble-Teran Maria E.; Hochberg David; Ribo Josep M.; Crusats Joaquim; Micheau Jean-Claude;
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作者单位

Univ Autonoma Estado Morelos Ctr Invest Quim IICBA Cuernavaca 62209 Morelos Mexico;

Univ Autonoma Chiapas Fac Ciencias Fis &

Matemat Tuxtla Gutierrez 29050 Chiapas Mexico;

Univ Autonoma Estado Morelos Ctr Invest Quim IICBA Cuernavaca 62209 Morelos Mexico;

Ctr Astrobiol CSIC INTA Dept Mol Evolut Madrid 28850 Spain;

Univ Barcelona Inst Ciencies Cosmos IEEC ICC Barcelona 08028 Catalunya Spain;

Univ Barcelona Inst Ciencies Cosmos IEEC ICC Barcelona 08028 Catalunya Spain;

Univ Paul Sabatier Lab IMRCP UMR CNRS 5623 F-31062 Toulouse France;

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中图分类化学;
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4. Ultrasound-Enhanced Deracemization: Toward the Existence of Agonist Effects in the Interpretation of Spontaneous Symmetry Breaking [J] . Rougeot Celine, Guillen Frederic, Plaquevent Jean-Christophe, Crystal growth & design . 2015,第5期

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5. Deracemization Controlled by Reaction-Induced Nucleation: Viedma Ripening as a Safety Catch for Total Spontaneous Resolution [J] . Steendam Rene R. E., van Benthem Tim J. B., Huijs Evelien M. E., Crystal growth & design . 2015,第8期

机译：反应诱导成核控制的脱团作用：Viedma成熟作为获得总自发分辨率的安全措施
6. Computational investigation of the influence of the initial conditions on solid state deracemization experiments [C] . M. Iggland, M. Mazzotti International Symposium on Industrial Crystallization . 2014

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8. Highly enantioselective synthesis of (R)-13-butanediol via deracemization of the corresponding racemate by a whole-cell stereoinverting cascade system [O] . Han Zu, Jie Gu, Hui Zhang, 2020

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机译：共结晶诱导的自发剥离化：一种通用的剥削热力学方法。
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