Development of Molecular Transformations on the Basis of Catalytic Generation of Anionic Species by Organosuperbase

Kondoh Azusa; Terada Masahiro

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Development of Molecular Transformations on the Basis of Catalytic Generation of Anionic Species by Organosuperbase

机译：有机培育基础基于催化生成阴离子物种的分子转化的发展

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In this account, we summarized our recent efforts to develop molecular transformations under Bronsted base catalysis on the basis of our own guiding principles for designing reaction systems, that include "the generation and application of anionic species which are difficult to utilize in conventional reaction systems" and "the employment of organosuperbases possessing much higher basicities than conventional organic bases as a catalyst". In particular, we discussed reactions involving the generation of carbanions of less acidic compounds through the formal umpolung process from carbonyl compounds and formal [3+2] cycloadditions involving the generation of the synthetic equivalent of a 1,3-dipole through epoxide opening.

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来源
《Bulletin of the Chemical Society of Japan》 |2021年第1期|共18页
作者
Kondoh Azusa; Terada Masahiro;
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作者单位

Tohoku Univ Res &

Analyt Ctr Giant Mol Grad Sch Sci Aoba Ku Sendai Miyagi 9808578 Japan;

Tohoku Univ Grad Sch Sci Dept Chem Aoba Ku Sendai Miyagi 9808578 Japan;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Anionic species; Organocatalysis; Organosuperbase;

机译：阴离子物种;有机成分;有机核酸;

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10. Development of Molecular Transformations on the Basis of Catalytic Generation of Anionic Species by Organosuperbase [O] . Azusa Kondoh, Masahiro Terada 2021

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机译：非催化和催化多孔介质中气态物质的传质和化学反应，支持催化和非催化液体

Development of Molecular Transformations on the Basis of Catalytic Generation of Anionic Species by Organosuperbase

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