Light control of radical modular synthesis

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Light control of radical modular synthesis

机译：轻型控制自由基模块化合成

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Polycyclic aromatic(di)imides are a ubiquitous structural motif in organic dyes and find wide application in organic light-emitters and photovoltaic cells.On the other hand,the phenalene motif,in which three aryl rings share three C-C bonds,is important in organic spin chemistry,having an uneven number of electrons in its neutral state,rendering it a neutral radical.Now,researchers in the Soft Matter Materials Laboratory at the Queensland University of Technology,in collaboration with the Max Plank Institute for Polymer Research and the Karlsruhe Institute of Technology(Germany),have pioneered a wavelength-gated synthesis that combines these two structural motifs into one scaffold named a phenalene diimide(Feist F.,Walden S.L.,ALves J.,Kunz S.V.,Micallef A.S.,Brock A.J.,McMurtrie J.C.,WeilT.,Blinco J.P.,Barner-Kowollik C.Angew.Chem.Int.Ed.2021,60,10402-8).

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《Chemistry in Australia》 |2021年第junaaauga期|共1页
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中图分类化学;化学工业;
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机译：可控自由基聚合法合成定义明确的聚合物

Light control of radical modular synthesis

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