...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>ACS Sustainable Chemistry & Engineering >Photocurable, Thermally Reprocessable, and Chemically Recyclable Vanillin-Based Imine Thermosets
【24h】

Photocurable, Thermally Reprocessable, and Chemically Recyclable Vanillin-Based Imine Thermosets

机译：可光固化，热再循环和化学可回收的香草蛋白的亚胺热固性剂

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Two vanillin-based photocurable, thermally reprocessable, and chemically recyclable imine thermosets were successfully designed. The vanillin vitrimer resins were synthesized through a protocol with a two-step reaction: methacrylation and imination with diamine or triamine. The obtained vinyl ester resins with imine bonds and vinyl groups could be photocured into thermosets in 10 min at room temperature. The cured thermosets had good solvent resistance against common solvents, good thermal stability up to about 250 °C as measured by thermogravimetry, and high storage modulus (1.6–3.4 GPa as determined by dynamic mechanical analysis). Owing to the reversibility of the imine bond, both thermosets exhibited typical vitrimer behavior including stress relaxation and thermal reprocessability, while their activation energy for the imine exchange reaction and recovery ratio of tensile stress after reprocessing varied due to different cross-linking densities. Furthermore, both thermosets could be chemically recycled in hexylamine through an imine exchange reaction. The presented new strategy, thus, paves the way for production of fast-curing, chemically and thermally stable, but still thermally reprocessable and chemically recyclable imine vitrimers from abundant biobased building blocks.
机译：None

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号