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首页> 外文期刊>Crystallography reports >The Influence of Cation Substitution on the Kinetics of Phase Transitions in Crystals of (K,NH4)(3)H(SO4)(2) Solid Solutions
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The Influence of Cation Substitution on the Kinetics of Phase Transitions in Crystals of (K,NH4)(3)H(SO4)(2) Solid Solutions

机译:阳离子取代对(k,NH4)(3)H(SO 4)(2)固溶体晶体晶体动力学的影响

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摘要

The structure of (K-0.967(NH4)(0.033))(3)H(SO4)(2) crystals, belonging to the K3H(SO4)(2)-(NH4)(3)H(SO4)(2)-H2O salt system, has been investigated by X-ray structural analysis. The room-temperature characteristics of the atomic structure of these crystals are found to be as follows: sp. gr. C2/c, Z = 4, a = 14.7025(4) angstrom, b = 5.6859(2) angstrom, c = 9.7885(3) angstrom , and R/wR = 0.021/0.030%. The thermal and optical properties of (K,NH4)(3)H(SO4)(2) and K3H(SO4)(2) single crystals have been investigated and compared in a temperature range of 295-500 K.
机译:None

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  • 来源
    《Crystallography reports》 |2018年第2期|共8页
  • 作者单位

    Russian Acad Sci Shubnikov Inst Crystallog Fed Sci Res Ctr Crystallog &

    Photon Moscow 119333 Russia;

    Russian Acad Sci Shubnikov Inst Crystallog Fed Sci Res Ctr Crystallog &

    Photon Moscow 119333 Russia;

    Russian Acad Sci Shubnikov Inst Crystallog Fed Sci Res Ctr Crystallog &

    Photon Moscow 119333 Russia;

    Russian Acad Sci Shubnikov Inst Crystallog Fed Sci Res Ctr Crystallog &

    Photon Moscow 119333 Russia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
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