Synthesis and Crystal Structure of a Zinc Coordination Polymer Based on Bis(4-(2 '-methylimidazol)phenyl)sulfone and (1,1 '-Biphenyl)-2,2 '-dicarboxylate Ligands

Wang G-F; Liu Y-Z

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Synthesis and Crystal Structure of a Zinc Coordination Polymer Based on Bis(4-(2 '-methylimidazol)phenyl)sulfone and (1,1 '-Biphenyl)-2,2 '-dicarboxylate Ligands

机译：基于双双（4-（2'-甲基咪唑）苯基）砜的锌配位聚合物的合成和晶体结构（1,1' - 苯基）-2,2'-二羧酸盐配体

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Zinc coordination polymer with V-shaped ligands, {[Zn(L-1) center dot (bpda)] center dot H2O}(n), (1) (L-1 = bis(4-(2'-methylimidazol)phenyl)sulfone, H(2)bpda = (1,1'-biphenyl)-2,2'-dicarboxylic acid) was synthesized under solvothermal condition. The structure of 1 was determined by single-crystal X-ray diffraction analysis and further characterized by infrared spectra and elemental analyses. In 1, the Zn(II) ion is four-coordinated by two nitrogen atoms of two distinct L-1 ligands and two oxygen atoms of two bpda(2-) to form a distorted tetrahedron. Complex 1 displays a 2D four-connected framework with a (6(5) x 8) topology along c direction.

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《Crystallography reports》 |2020年第6期|共4页
作者
Wang G-F; Liu Y-Z;
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Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Chinese Acad Sci Suzhou Inst Biomed Engn &

Technol Suzhou 215163 Peoples R China;

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正文语种 eng
中图分类晶体学;
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Synthesis and Crystal Structure of a Zinc Coordination Polymer Based on Bis(4-(2 '-methylimidazol)phenyl)sulfone and (1,1 '-Biphenyl)-2,2 '-dicarboxylate Ligands

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