Homoleptic Lanthanide Amide Catalysts for Organic Synthesis: Experiment and Theory

Rachel D.  Dicken; Alessandro  Motta; Tobin J.  Marks

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Homoleptic Lanthanide Amide Catalysts for Organic Synthesis: Experiment and Theory

机译：用于有机合成的经络镧系酰胺催化剂：实验与理论

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Homoleptic lanthanide trisamides provide a simple and highly accessible bridge between organolanthanide chemistry and the synthetic methodology community, and although they have proven to be competent catalysts in a wide variety of unique transformations, their reactivity, scope, and mechanism remain understudied relative to lanthanide metallocenes and related organometallic catalysts. In this Perspective, we provide a critical review of the recent advances in homoleptic lanthanide-mediated catalysis as they apply to atom-efficient and environmentally benign organic syntheses. Instead of an exhaustive review, we focus on selected examples of the unexpected reactivity displayed by readily available Ln[N(SiMe_(3))_(2)]_(3) complexes. By focusing on both the experimental as well as theoretical and mechanistic aspects of this work, we seek to highlight the value, versatility, and underlying concepts governing the unusual catalytic properties of homoleptic lanthanide amides and offer a general outlook on the prospects for this field.

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来源
《ACS catalysis》 |2021年第5期|共20页
作者
Rachel D. Dicken; Alessandro Motta; Tobin J. Marks;
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作者单位

Department of Chemistry Northwestern University;

Dipartimento di Scienze Chimiche Università di Roma “La Sapienza” and INSTM UdR Roma Piazzale Aldo Moro;

Department of Chemistry Northwestern University;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
lanthanides; homogeneous catalysis; trisamide complexes; organic synthesis;

机译：镧系;均匀催化;三胺络合物;有机合成;

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2. 2-27 A Density Functional Theory Study on Amide-substituted Phenanthroline Ligands for the Separation of Lanthanides and Actinides [J] . Cao, Shiwei, Wang, 中国科学院近代物理研究所和兰州重离子研究装置年报：英文版 . 2015,第001期
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Homoleptic Lanthanide Amide Catalysts for Organic Synthesis: Experiment and Theory

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