Fe3O4@GlcA@Cu-MOF: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides

Arash  Ghorbani-Choghamarani; Zahra  Taherinia

首页> 外文期刊>ACS combinatorial science >Fe3O4@GlcA@Cu-MOF: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides

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Fe3O4@GlcA@Cu-MOF: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides

机译：Fe3O4 @ glca @ cu-mof：一种磁性金属 - 有机框架，作为腈水合的可收回催化剂，并减少异硫氰酸酯，异氰酸酯和异氰酸酯

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摘要

A novel magnetic metal–organic framework (Fe_(3)O_(4)@[email?protected]) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and isocyanides with excellent activity and selectivity without any additional reducing agent.

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来源
《ACS combinatorial science》 |2020年第12期|共8页
作者
Arash Ghorbani-Choghamarani; Zahra Taherinia;
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作者单位

Department of Organic Chemistry Faculty of Chemistry Bu-Ali Sina University;

Department of Organic Chemistry Faculty of Chemistry Bu-Ali Sina University;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
nitrile hydration; reduction of isothiocyanates; isocyanates; isocyanides; gluconic acid; 4-phenylurazole;

机译：丁腈水合;还原异硫氰酸酯;异氰酸酯;异氰酸酯;葡萄糖酸;4-苯基脲;

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2. Highly efficient multi-metal catalysts for carbon dioxide reduction prepared from atomically sequenced metal organic frameworks [J] . Celia Castillo-Blas, Consuelo (A)lvarez-Galván, Inés Puente-Orench, 纳米研究（英文版） . 2021,第002期
3. Nitrogen-rich metal-organic framework mediated Cu-N-C composite catalysts for the electrochemical reduction of CO_(2) [J] . Si-Min Cao, Hua-Bo Chen, Bao-Xia Dong, 能源化学：英文版 . 2021,第003期
4. Nitrogen-rich metal-organic framework mediated Cu-N-C composite catalysts for the electrochemical reduction of CO2 [J] . Si-Min Cao, Wen-Long Liu, Hua-Bo Chen, 天然气化学（英文版） . 2021,第003期
5. Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective catalytic reduction of NO with NH3 [J] . 化学科学与工程前沿：英文版 . 2017,第004期
6. Single-Site Cobalt Catalysts at New Zr_(12)(μ_3-O)_8(μ_3-OH)_8(μ2-OH)_6 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Nitroarenes, Nitriles, and Isocyanides [J] . Pengfei Ji, Kuntal Manna, Zekai Lin, Journal of the American Chemical Society . 2017,第20期

机译：新型Zr_（12）（μ_3-O）_8（μ_3-OH）_8（μ2-OH）_6金属有机骨架节点上的单点钴催化剂，用于硝基芳烃，腈和异氰酸酯的高活性加氢
7. Recoverable and recyclable gas hydrate inhibitors based on magnetic nanoparticle-decorated metal-organic frameworks [J] . Lee Dongyoung, Jeoung Sungeun, Moon Hoi Ri, Chemical engineering journal . 2020,第1期

机译：基于磁性纳米粒子装饰金属 - 有机框架的可回收和可回收的天然气水合物抑制剂
8. La-Metal-Organic Framework incorporating Fe3O4 nanoparticles, post-synthetically modified with Schiff base and Pd. A highly active, magnetically recoverable, recyclable catalyst for C-C cross-couplings at low Pd loadings [J] . Xiong Gang, Chen Xiao-Ling, You Li-Xin, Journal of Catalysis . 2018,第期

机译：La-Metal-有机框架掺入Fe3O4纳米粒子，用Schiff Base和Pd合成改性。低PD载荷的C-C交叉耦合的高活性，可磁力可回收的可回收催化剂
9. Non-platinum metal-organic framework based electro-catalyst for promoting oxygen reduction reaction [C] . Dipanwita Das, Vrushali Raut, Kota V. M. K. Kireeti, DAE Solid State Physics Symposium . 2018

机译：基于非铂金属 - 有机框架的电催化剂，用于促进氧还原反应
10. Growth of organic films on semiconductor surfaces: Fundamental reactivity studies and molecular layer deposition involving isocyanates and isothiocyanates. [D] . Loscutoff, Paul W. 2010

机译：半导体表面上有机膜的生长：涉及异氰酸酯和异硫氰酸酯的基础反应性研究和分子层沉积。
11. Metal–Organic‐Framework‐Derived Dual Metal‐ and Nitrogen‐Doped Carbon as Efficient and Robust Oxygen Reduction Reaction Catalysts for Microbial Fuel Cells [O] . Haolin Tang, Shichang Cai, Shilei Xie, 2016

机译：金属-有机框架衍生的双金属和氮掺杂碳可作为微生物燃料电池的高效稳健的氧还原反应催化剂
12. Fe3O4@GlcA@Cu-MOF: A Magnetic MetalOrganic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides [O] . -1

机译：Fe3O4 @ glca @ cu-mof：磁性金属有机框架作为可恢复催化剂，用于水合腈，还原异硫氰酸酯，异氰酸酯和异氰酸酯
13. Contaminants of Magnetic Metals Recovered from Municipal Solid Waste:Tin,Aluminum,Organic Materials, [R] . duckett, e. joseph 1978

机译：从城市固体废物中回收的磁性金属污染物：锡，铝，有机材料，

Fe3O4@GlcA@Cu-MOF: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides

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