...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>ACS Macro Letters >100th Anniversary of Macromolecular Science Viewpoint: The Past, Present, and Future of Stereocontrolled Vinyl Polymerization
【24h】

100th Anniversary of Macromolecular Science Viewpoint: The Past, Present, and Future of Stereocontrolled Vinyl Polymerization

机译：大分子科学观点100周年：立体控制乙烯基聚合的过去，存在和未来

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The thermomechanical properties exhibited by synthetic macromolecules can be directly linked to their tacticity, or the relative stereochemistry of repeat units. The development of stereoselective coordination–insertion polymerization, for example, led to the discovery of isotactic polypropylene, now one of the most widely produced commodity plastics in the world. Widespread interest in controlling polymer tacticity has led to a variety of stereoselective polymerization methodologies; however, this area of polymer science has lagged behind when compared to the ability to control molecular weight, dispersity, and composition. Despite decades of advancements, many stereoregular vinyl polymers remain unknown, particularly those comprised of polar functionality or derived from renewable resources. This Viewpoint provides an overview of recent developments in stereocontrolled polymerization, with an emphasis on propagation mechanism, and highlights successes, limitations, and future challenges for continued innovation.
机译：None

著录项

  • 来源
    《ACS Macro Letters》 |2020年第11期|共17页
  • 作者

    Aaron J. Teator; Travis P. Varner; Phil C. Knutson; Cole C. Sorensen; Frank A. Leibfarth;

  • 作者单位

    Department of Chemistry The University of North Carolina at Chapel Hill;

    Department of Chemistry The University of North Carolina at Chapel Hill;

    Department of Chemistry The University of North Carolina at Chapel Hill;

    Department of Chemistry The University of North Carolina at Chapel Hill;

    Department of Chemistry The University of North Carolina at Chapel Hill;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号