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首页> 外文期刊>Inorganic Chemistry Communications >Thermal and light induced spin crossover in a mononuclear iron(II) complex
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Thermal and light induced spin crossover in a mononuclear iron(II) complex

机译：在单核铁（II）复合物中的热敏和光诱导旋转交叉

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AbstractA mononuclear complex {Fe(L)2[N(CN)2]2} (1) has been synthesized through the reaction of (naphth-1-yl)-N-(3,5-di(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)methanimine (L) with Fe[N(CN)2]2. Magnetic measurement reveals that1exhibits a thermal induced one-step spin crossover behavior with transition temperature T1/2of 75K. Furthermore, the light induced excited spin state trapping effect is observed on1.Graphical abstractA mononuclear spin crossover complex {Fe(L)2[N(CN)2]2} has been synthesized based on (naphth-1-yl)-N-(3,5-di(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)methanimine. Thermal and light induced spin transition between the HS and the LS state was observed on Fe(II) ion.Display OmittedHighlights?A mononuclear iron(II) spin crossover complex was synthesized.?Thermal and light induced spin crossover was achieved.?An incomplete spin crossover was observed.]]>
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