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首页> 外文期刊>Inorganic Chemistry Communications >Two flexible bis(pyrazole)-bis(amide) ligand directed beta-octamolybdate-based metal-organic complexes with different adsorption activities towards organic dyes and electrocatalytic properties
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Two flexible bis(pyrazole)-bis(amide) ligand directed beta-octamolybdate-based metal-organic complexes with different adsorption activities towards organic dyes and electrocatalytic properties

机译：两种柔性BIS（吡唑） - 释放（酰胺）配体，指导β-八谷族基金属 - 有机配合物，其具有不同的吸附活性，朝向有机染料和电催化性能

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摘要

Two octamolybdate-based metal-organic complexes (MOCs) constructed from two flexible bis(pyrazole)-bis (amide) ligands, Ni(L-1)(H2O)[beta-Mo8O26](0.5) (1) and Ni(L-2)(H2O)[beta-Mo8O26](0.5) (2) (L-1 = N, N-bis(3-pyrazolamide)-1,2-ethane, L-2 = N, N-bis(3-pyrazolamide)-1,2-propane), have been prepared under hydrothermal conditions. Complexes 1 and 2 are isostructural and both of them present 1D chain structures, which are composed of [beta-Mo8O26](4-) anions and metal-organic loops [Ni-2(L)(2)](4+) with different size. The complex 2 represents the first example of MOCs constructed from flexible bis(pyrazole)-bis(amide) L-2 ligand. Complexes 1 and 2 show different adsorption behaviors towards methylene blue. Their electrocatalytic properties were investigated.
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