Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se9

Qi Fei-Yan; Shele Muge; Baiyin Menghe

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Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se9

机译：CS4SB4S8和CS3SB5SE9的两种三元锑 - 胆碱

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Two ternary antimony-chalcogenides of Cs4Sb4S8 (1) and Cs3Sb5Se9 (2), were synthesized in organic solvent under solvothermal conditions. Single-crystal X-ray diffraction analyses showed that compound 1 is characterized by an infinite [Sb2S8]nn- chain formed by the alternating connection of two [Sb(1)S3] pyramidal and two [Sb(2)S4] tetrahedral. In compound 2, the [Sb2Se5]nn- chain is interconnected by the two octahedral [Sb(3)Se6] units via corner-sharing, and the [Sb3Se5]- ribbon is interconnected by two [Sb2Se5]nn- chains and pyramidal [Sb(5)Se3] unit via corner-sharing, finally, the[Sb5Se9]n3n- layer interconnected by [Sb3Se5]- ribbon and [Sb2Se5] dimer via corner-sharing. As estimated from the solid-state absorption spectra, the band gaps of 1 and 2 are 2.11 and 1.54 eV, respectively.

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来源
《Inorganic Chemistry Communications》 |2021年第1期|共5页
作者
Qi Fei-Yan; Shele Muge; Baiyin Menghe;
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作者单位

Inner Mongolia Normal Univ Coll Chem &

Environm Sci Hohhot 010022 Inner Mongolia Peoples R China;

Inner Mongolia Normal Univ Coll Chem &

Environm Sci Hohhot 010022 Inner Mongolia Peoples R China;

Inner Mongolia Normal Univ Coll Chem &

Environm Sci Hohhot 010022 Inner Mongolia Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Antimony-chalcogenides; Solvothermal synthesis; Crystal structure;

机译：锑 - 硫属化合物;溶剂热合成;晶体结构;

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Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se9

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