Supramolecular polymerization of Pt(II) complex with terpyridine-based ligand possessing alanine moiety in nonpolar solvent

Park Jaehyeon; Hwang Minkyeong; Ok Mirae; Li Chenxing; Choi Heekyoung; Seo Moo Lyong; Jung Jong Hwa

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Supramolecular polymerization of Pt(II) complex with terpyridine-based ligand possessing alanine moiety in nonpolar solvent

机译：Pt（II）复合物的超分子聚合与非极性溶剂中的丙啶基配体具有丙啶部分的络合物

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We report on the supramolecular polymerization of Pt(II) complex with terpyridine-based ligand (1) possessing alanine moiety in nonpolar solvents, such as methylcyclohexane, n-hexane, chloroform, and dichloromethane. The supramolecular polymer 1-Pt exhibited a strong orange emission as low as micromole concentration, which originated from the MLCT of 1-Pt in J-aggregation. The lifetime of supramolecular polymer 1-Pt was 0.5-2.1 mu s in nonpolar solvents. The supramolecular polymer 1-Pt showed a typical fiber structure using scanning electron microscopy (SEM) observation. Besides, the supramolecular polymer 1-Pt was generated by a cooperative pathway involving a nucleation-elongation mechanism.

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来源
《Inorganic Chemistry Communications》 |2021年第1期|共5页
作者
Park Jaehyeon; Hwang Minkyeong; Ok Mirae; Li Chenxing; Choi Heekyoung; Seo Moo Lyong; Jung Jong Hwa;
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作者单位

Gyeongsang Natl Univ Dept Chem Jinju 52828 South Korea;

Gyeongsang Natl Univ Dept Chem Jinju 52828 South Korea;

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原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Terpyridine; Pt(II) complex; Supramolecular polymer;

机译：Terpyridine;Pt（II）复合物;超分子聚合物;

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Supramolecular polymerization of Pt(II) complex with terpyridine-based ligand possessing alanine moiety in nonpolar solvent

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