On the early thermodynamic and kinetic deductions of the equilibrium constant equation

Quilez Juan

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On the early thermodynamic and kinetic deductions of the equilibrium constant equation

机译：关于平衡恒定方程的早期热力学和动力学折扣

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摘要

After briefly presenting the first formulation of the equilibrium constant stated by Guldberg and Waage, this study examines the early thermodynamic and kinetic deductions of the equilibrium law. Firstly, it is discussed how Horstmann applied the concept of entropy to chemical equilibrium reactions, which meant the first thermodynamic explanation of the Guldberg-Waage law of mass action proposed in 1864. A different theoretical derivation of the equilibrium constant came from the works of van't Hoff. This study analyses the first accurate kinetic treatment of equilibrium reactions as well as van't Hoff's imaginative thermodynamic foundation of the constant ratios in chemical equilibrium systems.

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来源
《Foundations of chemistry》 |2021年第1期|共19页
作者
Quilez Juan;
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作者单位

Univ Jaume 1 Dept Educ Castellon de La Plana 12071 Spain;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Equilibrium law; Mathematical reasoning; Chemical thermodynamics; Chemical kinetics; Physical chemistry;

机译：均衡法;数学推理;化学热力学;化学动力学;物理化学;

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On the early thermodynamic and kinetic deductions of the equilibrium constant equation

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