Mathematical Modeling of Free Radical Solution Terpolymerization Reactions in a Batch and Continuous Flow Stirred Tank Reactors

Luciani Carla V.; Choi Kyu Yong

首页> 外文期刊>Macromolecular theory and simulations >Mathematical Modeling of Free Radical Solution Terpolymerization Reactions in a Batch and Continuous Flow Stirred Tank Reactors

【24h】

Mathematical Modeling of Free Radical Solution Terpolymerization Reactions in a Batch and Continuous Flow Stirred Tank Reactors

机译：分批和连续流动搅拌釜反应器中自由基溶液三聚合反应的数学建模

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A mathematical model that describes a free radical solution terpolymerization is applied to styrene (St), methyl methacrylate (MMA), and maleic anhydride (MAh) polymerization system. This terpolymerization model allows for the use of either monofunctional or bifunctional peroxide initiators, and it is applied to batch and continuous reactions. The key model outputs are global monomer conversion, terpolymer composition, terpolymer average molecular weights, and terpolymer monomer sequence distributions. A few kinetic parameters are estimated such that global conversion is properly predicted by the model including initiator efficiency and two termination rate constants. Molecular weights are shown to be dominated by chain transfer reactions. Experimental trends of conversion, terpolymer molar masses (molecular weights), and composition are reasonably well predicted by the model.

机译：None

著录项

来源
《Macromolecular theory and simulations》 |2021年第3期|共12页
作者
Luciani Carla V.; Choi Kyu Yong;
展开▼
作者单位

Univ Maryland Dept Chem &

Biomol Engn College Pk MD 20742 USA;

Univ Maryland Dept Chem &

Biomol Engn College Pk MD 20742 USA;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类高分子化学（高聚物）;
关键词
terpolymerization; free radical polymerization; kinetics; modeling;

机译：三聚合;自由基聚合;动力学;建模;

相似文献

外文文献
中文文献
专利

1. CFD modeling of turbulent reacting flow in a semi-batch stirred-tank reactor [J] . Xiaoxia Duan, Xin Feng, Chao Yang, 中国化学工程学报（英文版） . 2018,第004期
2. Modeling and Control of a Continuous Stirred Tank Reactor Based on a Mixed Logical Dynamical Model [J] . 杜静静, 宋春跃, 李平中国化学工程学报：英文版 . 2007,第004期
3. Egg-like magnetically immobilized nanospheres： A long- lived catalyst model for the hydrogen transfer reaction in a continuous-flow reactor [J] . Yongjian Ai12, Zenan Hu1, Zixing Shao2, 纳米研究：英文版 . 2018,第001期
4. Egg-like magnetically immobilized nanospheres: A long-lived catalyst model for the hydrogen transfer reaction in a continuous-flow reactor [J] . Yongjian Ai, Zenan Hu, Zixing Shao, 纳米研究（英文版） . 2018,第001期
5. Immersion and invariance adaptive control of a class of continuous stirred tank reactors [J] . Gaiyan HONG, Xiangbin LIU, Hongye SU 控制理论与应用（英文版） . 2015,第001期
6. From batch to continuous free-radical solution polymerization of acrylic acid using a stirred tank reactor [J] . Juri Ilare, Mattia Sponchioni, Giuseppe Storti Reaction Chemistry & Engineering . 2020,第11期

机译：从批量到连续自由基溶液聚合丙烯酸使用搅拌釜反应器
7. Methyl Esters Selectivity of Transesterification Reaction with Homogenous Alkaline Catalyst to Produce Biodiesel in Batch, Plug Flow, and Continuous Stirred Tank Reactors [J] . N. F.Nasir, W. R. W.Daud, S. K.Kamarudin, International journal of chemical engineering . 2014,第1期

机译：甲酯选择酯交换反应与均匀碱性催化剂，以分批，塞流和连续搅拌釜反应器产生生物柴油
8. Methyl Esters Selectivity of Transesterification Reaction with Homogenous Alkaline Catalyst to Produce Biodiesel in Batch, Plug Flow, and Continuous Stirred Tank Reactors [J] . N. F. Nasir, W. R. W. Daud, S. K. Kamarudin International journal of chemical engineering . 2014,第Null期

机译：与均相碱性催化剂进行酯交换反应的甲基酯选择性，可分批，推流和连续搅拌釜反应器生产生物柴油
9. Mathematical modeling of limestone dissolution in batch stirred tank reactors in presence of a diluted strong acid. [C] . Cataldo De Blasio, Jarl Ahlbeck, Frej Bjondahl European Symposium on Computer Aided Process Engineering . 2008

机译：在稀释的强酸存在下批量搅拌釜反应器中石灰石溶解的数学建模。
10. FREE-RADICAL POLYMERIZATION OF VINYL ACETATE IN BATCH AND CONTINUOUS STIRRED TANK REACTORS. [D] . CHATTERJEE, ASOKE. 1975

机译：批量和连续搅拌釜反应器中乙酸乙烯酯的自由基聚合。
11. Synthesis of Lactulose in Continuous Stirred Tank Reactor With β-Galactosidase of Apergillus oryzae Immobilized in Monofunctional Glyoxyl Agarose Support [O] . Claudia Ubilla, Nicolás Ramírez, Felipe Valdivia, 2020

机译：用β-半乳糖苷酶固定在单官能乙醛琼脂糖烷基中的β-半乳糖苷酶中连续搅拌釜反应器的合成
12. Polymerisation of vinyl monomers in continuous-flow reactors. An experimental study, which includes digital computer modelling, of the homopolymerisation of styrene and methylmethacrylate by anionic and free radical mechanisms respectively in continuous flow-stirred-tank reactors. [O] . Bourikas N. 1976

机译：连续流反应器中乙烯基单体的聚合。一项包括数字计算机建模在内的实验研究，分别是在连续流动搅拌釜式反应器中，通过阴离子和自由基机理分别进行苯乙烯和甲基丙烯酸甲酯的均聚反应。
13. Continuous Stirred Tank Reactor Investigation of the Gas-Phase Reaction of Hydroxyl Radicals and Toluene [R] . Gery, M. W. , Fox, D. L. , Jeffries, H. E. , 1985

机译：连续搅拌釜反应器研究羟基自由基与甲苯的气相反应

Mathematical Modeling of Free Radical Solution Terpolymerization Reactions in a Batch and Continuous Flow Stirred Tank Reactors

摘要

著录项

相似文献

相关主题

期刊订阅